fac-Re(NPh)Cl₃(dppf)

Base Information

• Chemical Name: fac-Re(NPh)Cl₃(dppf)
• CAS No.: 256954-13-9
• Molecular Formula: C₄₀H₃₃Cl₃FeNP₂Re
• Molecular Weight: 938.069
• Mol file: 256954-13-9.mol

Synonyms:

Chemical Property of fac-Re(NPh)Cl₃(dppf)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of fac-Re(NPh)Cl₃(dppf)

There total 3 articles about fac-Re(NPh)Cl₃(dppf) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + trans-trichloro(phenylimido)bis(triphenylphosphine)rhenium(V) (62192-31-8) → fac-Re(NPh)Cl3(dppf) (256954-13-9)

Guidance literature:

In benzene; under Ar atm. benzene soln. mer,trans-ReCl3NPh)(PPh3)2 and dppf was refluxed for 1 h; ppt. was filtered off, washed with benzene, Et2O, and pentane and dried under vac.; elem. anal.;

DOI:10.1016/S0022-328X(01)00754-9

Reference yield:

fac-oxotrichloro[1,1'-bis(triphenylphosphine)ferrocene]rhenium(V) + N-phenyltriphenyliminophosphorane (2325-27-1) → fac-Re(NPh)Cl3(dppf) (256954-13-9)

Guidance literature:

In benzene; react. with PhN=PPh3 in refluxing benzene for 2-120 h;

DOI:10.1016/S0022-328X(01)00754-9

Reference yield:

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + trichloro(phenylimido)bis(triphenylphosphine)rhenium(V) → [Re(NPh)Cl3(1,1'-bis(diphenylphosphino)ferrocene)] (256954-13-9)

Guidance literature:

In dichloromethane; benzene; to suspn. of Re-complex in benzene-CH2Cl2 dppf was added with stirring, refluxed under N2 for 2 h; filtered, washed with MeOH, dried under N2; elem. anal.;

DOI:10.1016/S0022-328X(01)00917-2

upstream raw materials:

N-phenyltriphenyliminophosphorane

1,1'-bis-(diphenylphosphino)ferrocene

trans-trichloro(phenylimido)bis(triphenylphosphine)rhenium(V)

Downstream raw materials:

Re(NPh)(OEt)Cl₂(dppf)