tetrakis(acetonitrile-N)copper(I) hexafluorophosphate(V) acetonitrile solvate

Base Information

• Chemical Name: tetrakis(acetonitrile-N)copper(I) hexafluorophosphate(V) acetonitrile solvate
• CAS No.: 163317-51-9
• Molecular Formula: C₂H₃N*C₈H₁₂CuN₄*F₆P
• Molecular Weight: 413.773
• Mol file: 163317-51-9.mol

Synonyms:

Chemical Property of tetrakis(acetonitrile-N)copper(I) hexafluorophosphate(V) acetonitrile solvate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetrakis(acetonitrile-N)copper(I) hexafluorophosphate(V) acetonitrile solvate

There total 1 articles about tetrakis(acetonitrile-N)copper(I) hexafluorophosphate(V) acetonitrile solvate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.5%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + (1R,2R)-bis((2,6-dichlorobenzylidene)diamino)cyclohexane (155324-13-3) → tetrakis(acetonitrile-N)copper(I) hexafluorophosphate(V) acetonitrile solvate (163317-51-9) + CuC6H10N2C14H8Cl4(CH3CN)(1+)*Cu(C6H10(NCHC6H3Cl2)2)(NCCH3)2(1+)*Cu2(C6H10(NCHC6H3Cl2)2)3(2+)*4PF6(1-)*2CH2Cl2*3C2H5OC2H5

Guidance literature:

In dichloromethane; a soln. in CH2Cl2 was stirred for 10 min (inert atm.); filtered, reduced under vac., Et2O was added at -10°C; elem. anal.;

DOI:10.1021/om0003786

Reference yield:

tetrakis(acetonitrile-N)copper(I) hexafluorophosphate(V) acetonitrile solvate (163317-51-9) + triphenylphosphine (603-35-0) → acetonitriletris(triphenylphosphine)copper(I) hexafluorophosphate*(acetonitrile) (864154-17-6)

Guidance literature:

In ethanol; acetonitrile; Cu complex and PPh3 (molar ratio 1:3) dissolved in warm EtOH-MeCN; gently warmed; crystd. by cooling to room temp. and partial evapn.; elem. anal.;

DOI:10.1039/b505200a

upstream raw materials:

tetrakis(actonitrile)copper(I) hexafluorophosphate

(1R,2R)-bis((2,6-dichlorobenzylidene)diamino)cyclohexane

Downstream raw materials:

acetonitriletris(triphenylphosphine)copper(I) hexafluorophosphate*(acetonitrile)