iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)⁽¹⁺⁾

Base Information

• Chemical Name: iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)⁽¹⁺⁾
• CAS No.: 773788-18-4
• Molecular Formula: C₃₄H₃₃IP₃Pd
• Molecular Weight: 767.882
• Mol file: 773788-18-4.mol

Synonyms:

Chemical Property of iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)⁽¹⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)⁽¹⁺⁾

There total 2 articles about iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)⁽¹⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetonitrile(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate → iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)(1+) (773788-18-4)

Guidance literature:

Multi-step reaction with 2 steps

1: NaOH / water; acetonitrile; ethanol

2: chloroform

With NaOH; In ethanol; chloroform; water; acetonitrile;

DOI:10.1016/S0020-1693(02)00981-7

Reference yield:

1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate (493038-37-2) + tetra-(n-butyl)ammonium iodide (311-28-4) → iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)(1+) (773788-18-4)

Guidance literature:

In chloroform; under N2; react. of Pd complex with large excess of Bu4NI in CHCl3; monitored by (31)P NMR spectra; Kinetics;

DOI:10.1016/S0020-1693(02)00981-7

upstream raw materials:

1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate

tetra-(n-butyl)ammonium iodide