Cr(CO)5NH₂C₆H₄CH₃

Base Information

Chemical Name:Cr(CO)5NH₂C₆H₄CH₃
CAS No.:95583-11-2
Molecular Formula:C₁₂H₉CrNO₅
Molecular Weight:299.203
Hs Code.:

Cr(CO)5NH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>

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Chemical Property of Cr(CO)5NH₂C₆H₄CH₃

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Technology Process of Cr(CO)5NH₂C₆H₄CH₃

There total 1 articles about Cr(CO)5NH₂C₆H₄CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 108-44-1
1-amino-3-methylbenzene

: 95583-11-2
Cr(CO)5NH₂C₆H₄CH₃

Guidance literature:: With tetrahydrofuran; In tetrahydrofuran; Irradiation (UV/VIS); Cr(CO)6 was irradiated in THF at 0°C under N2 until max. possible amt. of (CO)5Cr(THF) was formed (IR control), resulting soln. was treated at 20°C with an equimol. amt. of amine; volatiles were removed under high vac., residue taken up in toluene, filtered, petroleum ether was added to the filtrate, cooled to -78°C, resulting crystals were filtered, washed with cold hexane, dried under high vac. for 8 h; elem. anal.;
DOI:10.1016/0022-328X(84)80723-8

Reference yield: 14.5%

: 95583-11-2
Cr(CO)5NH₂C₆H₄CH₃

: 95583-23-6
Cr(CO)5NHC₆H₃(CH₃)NC₆H₄(CH₃)

Guidance literature:: With lead(IV) acetate; In toluene; byproducts: Cr(CO)6; a toluene soln. of Cr-complex was treated with 2 equiv of Pb(OAc)4 at -20°C under N2; soln. was concd., filtered, chromd. on a SiO2 column (eluent toluene) at -20°C, eluate was evapd. under high vac., residue twice recrystd. from hexane at -20/-78°C; elem. anal.;
DOI:10.1016/0022-328X(84)80723-8