bis((triphenylsilyl)-η6-benzene)vanadium

Base Information

• Chemical Name: bis((triphenylsilyl)-η6-benzene)vanadium
• CAS No.: 125594-43-6
• Molecular Formula: C₄₈H₄₀Si₂V
• Molecular Weight: 723.958
• Mol file: 125594-43-6.mol

Synonyms:

Chemical Property of bis((triphenylsilyl)-η6-benzene)vanadium

Chemical Property:

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Technology Process of bis((triphenylsilyl)-η6-benzene)vanadium

There total 1 articles about bis((triphenylsilyl)-η6-benzene)vanadium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.7%

bis(η(6)-benzene)vanadium (12129-72-5) + N,N,N,N,-tetramethylethylenediamine (110-18-9) + Triphenylsilyl chloride (76-86-8) → bis((triphenylsilyl)-η6-benzene)vanadium (125594-43-6)

Guidance literature:

With n-butyllithium; In cyclohexane; (N2); dry solvents; addn. of n-BuLi to refluxing soln. of V-compd./TMEDA in C6H12, cooling to room temperature, stirring (12 h), removal of C6H12, addn. of petroleum ether, cooling to 0°C, addn. of ClSiPh3 with vigorous stirring; filtration, extn. (boiling toluene); elem. anal.;

upstream raw materials:

bis(η(6)-benzene)vanadium

N,N,N,N,-tetramethylethylenediamine

Triphenylsilyl chloride