[(C₅H₅)(CO)3W(HOCH(CH₃)2)]⁽¹⁺⁾*(B(C₆H₃(CF₃)2)4)^(1-)=[(C₅H₅)(CO)3W(HOCH(CH₃)2)](B(C₆H₃(CF₃)2)4)

Base Information

• Chemical Name: [(C₅H₅)(CO)3W(HOCH(CH₃)2)]⁽¹⁺⁾*(B(C₆H₃(CF₃)2)4)^(1-)=[(C₅H₅)(CO)3W(HOCH(CH₃)2)](B(C₆H₃(CF₃)2)4)
• CAS No.: 356785-21-2
• Molecular Formula: C₁₁H₁₃O₄W*C₃₂H₁₂BF₂₄
• Molecular Weight: 1256.29
• Mol file: 356785-21-2.mol

Synonyms:

Chemical Property of [(C₅H₅)(CO)3W(HOCH(CH₃)2)]⁽¹⁺⁾*(B(C₆H₃(CF₃)2)4)^(1-)=[(C₅H₅)(CO)3W(HOCH(CH₃)2)](B(C₆H₃(CF₃)2)4)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₅H₅)(CO)3W(HOCH(CH₃)2)]⁽¹⁺⁾*(B(C₆H₃(CF₃)2)4)^(1-)=[(C₅H₅)(CO)3W(HOCH(CH₃)2)](B(C₆H₃(CF₃)2)4)

There total 1 articles about [(C₅H₅)(CO)3W(HOCH(CH₃)2)]⁽¹⁺⁾*(B(C₆H₃(CF₃)2)4)^(1-)=[(C₅H₅)(CO)3W(HOCH(CH₃)2)](B(C₆H₃(CF₃)2)4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

tricarbonylcyclopentadienyltungsten(II) hydride (12128-26-6) + [H(OEt2)2][B(3,5-C6H3(CF3)2)4] (139362-04-2) + acetone (67-64-1) → [(C5H5)(CO)3W(HOCH(CH3)2)](1+)*(B(C6H3(CF3)2)4)(1-)=[(C5H5)(CO)3W(HOCH(CH3)2)](B(C6H3(CF3)2)4) (356785-21-2)

Guidance literature:

In toluene; (Ar); using Schlenk techniques; cooling of mixt. of Cp(CO)3WH, (H(Et2O)2)(B(C6H3(CF3)2)4) and toluene at -78°C, addn. of acetone, warmingto 22°C, stirring for 1 h; removal of solvent under vac., dissolving in Et2O, addn. slowly of hexane, pptn., washing with hexane, drying under vac., elem. anal.;

DOI:10.1021/om010222l

Reference yield:

[(C5H5)(CO)3W(HOCH(CH3)2)](1+)*(B(C6H3(CF3)2)4)(1-)=[(C5H5)(CO)3W(HOCH(CH3)2)](B(C6H3(CF3)2)4) (356785-21-2) + acetone (67-64-1) → [Cp(CO)3W(acetone)][B(C6H3(CF3)2)4] (356785-34-7)

Guidance literature:

In dichloromethane-d2; byproducts: isopropanol; (Ar); using Schlenk techniques; addn. of acetone (1 equiv.) to soln. of (Cp(CO)3W(HOi-Pr))(B(C6H3(CF3)2)4) (1 equiv.) in CD2Cl2 in NMR tube, holding for 5 d at 22°C; monitoring by NMR; Kinetics;

DOI:10.1021/om010222l

upstream raw materials:

tricarbonylcyclopentadienyltungsten(II) hydride

[H(OEt₂)₂][B(3,5-C₆H₃(CF₃)₂)₄]

acetone

Downstream raw materials:

[Cp(CO)3W(acetone)][B(C₆H₃(CF₃)2)4]