(S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene

Base Information

Chemical Name:(S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene
CAS No.:1177249-19-2
Molecular Formula:C₂₄H₃₆FeNP
Molecular Weight:425.377
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene

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Technology Process of (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene

There total 2 articles about (S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1262899-10-4
(S)-(-)-2-dicyclohexylphosphinothioyl-1-dimethylaminoferrocene

: 1177249-19-2,1262899-32-0
(S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene

Guidance literature:: With Ni-Al; In acetonitrile; (Ar); Schlenk technique; mixt. of Fe complex and Ni-Al catalyst in MeCN was heated at 60°C for 2 h; cooled to room temp.; filtered through Celite; washed (MeCN); chromd. (silica gel, hexane/Et2O, 90/10);
DOI:10.1016/j.jorganchem.2010.08.042

Reference yield: 77.0%

: 109-72-8,29786-93-4
n-butyllithium

: 67251-69-8
N,N-dimethylaminoferrocene

: 109-63-7
boron trifluoride diethyl etherate

: 16523-54-9
chlorodicyclohexylphosphane

: 1177249-19-2,1262899-32-0
2-dicyclohexylphosphino-1-dimethylaminoferrocene

Guidance literature:: In tetrahydrofuran; hexane; under Ar; BF3*Et2O added to soln. of ferrocene deriv. in THF at 0°C, after 15 min soln. of n-BuLi in hexanes added at -40°C, mixt.stirred for 1 h, PCy2Cl added, mixt. warmed to room temp.; Et2O added, soln. treated with satd. aq. NaHCO3, washed with water and brine, dried over Na2SO4, filtrate evapd., residue dissolved in pentane, chromy. (silica gel, pentane/Et2O (95/5)), evapn.; NMR, MS;
DOI:10.1021/om900422t

Reference yield: 99.0%

: 12112-67-3
bis(1,5-cyclooctadiene)diiridium(I) dichloride

: 1177249-19-2,1262899-32-0
(S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene

: 1262899-37-5
(S)-(-)-2-dicyclohexylphosphino-1-dimethylaminoferrocene iridium(cyclooctadiene) chloride

Guidance literature:: In dichloromethane; (Ar); Schlenk technique; soln. of Ir complex (0.5 equiv.) and Fe complexin CH2Cl2 was refluxed for 1.5 h; cooled to room temp.; concd.;
DOI:10.1016/j.jorganchem.2010.08.042