(Dichloromethyl)germane

Base Information

• Chemical Name: (Dichloromethyl)germane
• CAS No.: 1111-82-6
• Molecular Formula: CH4Cl2Ge
• Molecular Weight: 159.539
• DSSTox Substance ID: DTXSID00779961
• Mol file: 1111-82-6.mol

Synonyms:dichloromethyl-germane;(Dichloromethyl)germane;DTXSID00779961;1111-82-6

Chemical Property of (Dichloromethyl)germane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 156.8667082
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(Cl)(Cl)[Ge]

Technology Process of (Dichloromethyl)germane

There total 1 articles about (Dichloromethyl)germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetracarbonyldi(methylgermyl)iron → [Fe(CO)4(Ge(CH3)Cl)]2 (69480-66-6) + Fe(CO)4(Ge(CH3)Cl2)2 + [Fe(CO)4]2(Ge(CH3)H)(Ge(CH3)Cl) + dichloromethylgermane (1111-82-6) + methyltrichlorogermane (993-10-2)

Guidance literature:

With hydrogenchloride; In benzene; byproducts: H2, CO; in neat SiCl4, excess HCl, 5°C, 540 min; then room temp., 12 months (pptn.); product and intermediate ratio varying with reaction time ((1)H-NMR spectroscopy); further intermediate: Fe(CO)4H2; removal of volatiles, hand sepn. of crystals of (OC)4Fe(GeMeCl)2Fe(CO)4;

DOI:10.1039/DT9780001569