(Ph)(Me)Si((CH₂)3B(OH)2)2

Base Information

• Chemical Name: (Ph)(Me)Si((CH₂)3B(OH)2)2
• CAS No.: 1292360-20-3
• Molecular Formula: C₁₃H₂₄B₂O₄Si
• Molecular Weight: 294.039
• Mol file: 1292360-20-3.mol

Synonyms:

Chemical Property of (Ph)(Me)Si((CH₂)3B(OH)2)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Ph)(Me)Si((CH₂)3B(OH)2)2

There total 3 articles about (Ph)(Me)Si((CH₂)3B(OH)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

diallyl(methyl)(phenyl)silane (2633-60-5) + water (7732-18-5) + dibromoborane-methyl sulfide complex (55671-55-1,146732-64-1) → (Ph)(Me)Si((CH2)3B(OH)2)2 (1292360-20-3)

Guidance literature:

With H₂O; In dichloromethane; to HBBr2*SMe2 in CH2Cl2 added dropwise CH2Cl2 soln. of Si compd.; react.mixt. refluxed for 2 h; cooled to 0°C, hydrolyzed with H2O; stir red for 30 min at ambient temp.; solvent removed in vac.; solid isolated by suction filtration; washed with water; elem. anal.;

DOI:10.1016/j.jorganchem.2011.01.006

Reference yield:

(Ph)(Me)Si((CH2)3BBr2)2 → (Ph)(Me)Si((CH2)3B(OH)2)2 (1292360-20-3)

Guidance literature:

With water; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.jorganchem.2011.01.006

Reference yield:

diallyl(methyl)(phenyl)silane (2633-60-5) → (Ph)(Me)Si((CH2)3B(OH)2)2 (1292360-20-3)

Guidance literature:

Multi-step reaction with 2 steps

1: dibromoborane-methyl sulfide complex / dichloromethane / 2 h / Reflux; Inert atmosphere

2: water / dichloromethane / 0 - 20 °C / Inert atmosphere

With water; dibromoborane-methyl sulfide complex; In dichloromethane; 1: Hydroboration reaction;

DOI:10.1016/j.jorganchem.2011.01.006

upstream raw materials:

diallyl(methyl)(phenyl)silane

water

dibromoborane-methyl sulfide complex

Refernces