[(acetylacetonato)bis(benzoquinolinato-C²,N)iridium(III)] hexafluorophosphate

Base Information

Chemical Name:[(acetylacetonato)bis(benzoquinolinato-C²,N)iridium(III)] hexafluorophosphate
CAS No.:907590-93-6
Molecular Formula:C₃₁H₂₃IrN₂O₂
Molecular Weight:647.756
Hs Code.:

[(acetylacetonato)bis(benzoquinolinato-C<sup>2</sup>,N)iridium(III)] hexafluorophosphate

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Chemical Property of [(acetylacetonato)bis(benzoquinolinato-C²,N)iridium(III)] hexafluorophosphate

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Technology Process of [(acetylacetonato)bis(benzoquinolinato-C²,N)iridium(III)] hexafluorophosphate

There total 2 articles about [(acetylacetonato)bis(benzoquinolinato-C²,N)iridium(III)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 52352-02-0
tetrakis-(benzo[h]quinoline(-1H))-μ-(dichloro)-diiridium(III)

: 123-54-6,81235-32-7
acetylacetone

: 337526-87-1,907590-93-6
[(acetylacetonato)bis(benzoquinolinato-C²,N)iridium(III)] hexafluorophosphate

Guidance literature:: With sodum carbonate; In further solvent(s); ((bzq)2IrCl)2, 2,4-pentanedione, and Na2CO3 were refluxed under inert gas atm. in 2-ethoxyethanol for 12-15 h; mixt. was cooled to room temp., ppt. was filtered off. washed with water, Et2O, and hexane, chromy. on silica using CH2Cl2 as eluent; elem. anal.;
DOI:10.1021/ic0008969

Reference yield:

: 230-27-3
7,8-benzoquinoline

: 337526-87-1,907590-93-6
[(acetylacetonato)bis(benzoquinolinato-C²,N)iridium(III)] hexafluorophosphate

Guidance literature:: Multi-step reaction with 2 steps

1: 2-methoxy-ethanol; water / 14 h / 120 °C / Schlenk technique; Inert atmosphere

2: potassium carbonate / 2-ethoxy-ethanol / 24 h / 100 °C / Schlenk technique; Inert atmosphere

With potassium carbonate; In 2-ethoxy-ethanol; 2-methoxy-ethanol; water;
DOI:10.1016/j.jorganchem.2016.02.001