Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2

Base Information

Chemical Name:Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2
CAS No.:852287-60-6
Molecular Formula:C₇₆H₅₆O₁₂Ru₄
Molecular Weight:1565.55
Hs Code.:

Synonyms:

Suppliers and Price of Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2

There total 3 articles about Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.1%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 538-58-9
1,5-diphenyl-1,4-pentadiene-3-one

: Ru3(CO)6(μ3-η2-η2-η2-O=C(CH=CHPh)CH=CPh)2

: Ru3(CO)7(η2OC(CHCHPh)CH=CPh)2CHCPh)(μ-η-η4-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)(μ3-η-η-η4-(CH2Ph)...

: 852287-60-6
Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2

Guidance literature:: In n-heptane; under Ar; mixt. of Ru3(CO)12 and ligand (molar ratio 1:4) refluxed in heptane for 4 h; cooled to room temp.; filtered; filtrate column chromd. (silica gel, hexane-benzene 1:1), two Ru3 complexes sepd.; ppt. flushed with benzene (Ru4 complex); elem. anal.;
DOI:10.1021/om0489958

Reference yield: 13.8%

: Ru3(CO)7(η2OC(CHCHPh)CH=CPh)2CHCPh)(μ-η-η4-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)(μ3-η-η-η4-(CH2Ph)...

: 852287-60-6
Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2

Guidance literature:: With dibenzylideneacetone; In n-heptane; under Ar; mixt. of Ru complex and dibenzylideneacetone (molar ratio 1:2)refluxed in heptane for 2.5 h; cooled to room temp.; filtered; ppt. flushed with benzene;
DOI:10.1021/om0489958

Reference yield:

: 852287-57-1
Ru2(CO)4(η-acetone)(μ-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)

: 852287-60-6
Ru4(CO)8(μ3-η-η2-η6-OC(CHCHPh)CHCPhCH(CH2Ph)C(O)CHCHPh)2

Guidance literature:: In further solvent(s); byproducts: acetone; under Ar; hydrocarbon soln. of Ru complex stored for 1 d; ppt. of Ru4 complex obtained;
DOI:10.1021/om0489958