Diazenedicarboxylic acid, ethyl phenylmethyl ester

Base Information

• Chemical Name: Diazenedicarboxylic acid, ethyl phenylmethyl ester
• CAS No.: 111508-33-9
• Molecular Formula: C11H12N2O4
• Molecular Weight: 236.227
• Mol file: 111508-33-9.mol

Synonyms:

Chemical Property of Diazenedicarboxylic acid, ethyl phenylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diazenedicarboxylic acid, ethyl phenylmethyl ester

There total 2 articles about Diazenedicarboxylic acid, ethyl phenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

benzyl chloroformate (501-53-1,94274-21-2) + ethylhydrazine carboxylate (4114-31-2) → benzyl ethyl diazene-1,2-dicarboxylate (111508-33-9)

Guidance literature:

With tert-butylhypochlorite; In ethyl acetate; for 3h; Ambient temperature;

DOI:10.1039/P19870000877

Reference yield: 93.4%

1-benzyl 2-ethyl hydrazine-1,2-dicarboxylate (95028-42-5) → benzyl ethyl diazene-1,2-dicarboxylate (111508-33-9)

Guidance literature:

With tert-butylhypochlorite; In ethyl acetate; at 20 ℃; for 3h;

Reference yield: 100.0%

benzyl ethyl diazene-1,2-dicarboxylate (111508-33-9) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → benzyl ethyl 1,2,3,6-tetrahydropyridazine-1,2-dicarboxylate (111508-34-0)

Guidance literature:

In benzene; for 24h;

DOI:10.1039/P19870000877

upstream raw materials:

benzyl chloroformate

ethylhydrazine carboxylate

1-benzyl 2-ethyl hydrazine-1,2-dicarboxylate

Downstream raw materials:

benzyl ethyl 1,2,3,6-tetrahydropyridazine-1,2-dicarboxylate