((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2

Base Information

Chemical Name:((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2
CAS No.:241165-13-9
Molecular Formula:C₃₇H₅₉N₂Sc
Molecular Weight:576.845
Hs Code.:

((2,6-iPr<sub>2</sub>-C<sub>6</sub>H<sub>3</sub>)NC(tBu)CHC(tBu)N(2,6-iPr<sub>2</sub>-C<sub>6</sub>H<sub>3</sub>))Sc(methyl)2

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Chemical Property of ((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2

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Technology Process of ((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2

There total 1 articles about ((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 241165-09-3
[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

: 917-54-4
methyllithium

: 241165-13-9
((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2

Guidance literature:: In toluene; under Ar; toluene condensed into flask contg. Sc complex and MeLi at -78°C; mixt. warmed to room temp.; stirred for 1 h; filtered; solvent removed (vac.); residue recrystd. (hexane); elem. anal.;
DOI:10.1021/om010131o

Reference yield: 89.0%

: 241165-09-3
[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

: 241165-13-9
((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2

: 350609-81-3
Sc(C₃HN₂(C₄H₉)2(C₆H₃(C₃H₇)2)2)(CH₃)Cl

Guidance literature:: In toluene; under Ar; toluene was condensed into flask contg. Sc complexes at -78°C; graduelly warmed to room temp.; stirred for 90 min; solvent removed (vac.); hexane added; mixt. filtered; solvent removed (vac.); recrystd. (hexane) at -35°C; elem. anal.;
DOI:10.1021/om010131o

Reference yield: 72.0%

: 241165-13-9
((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2

: 165612-94-2
bis(pentafluorophenyl)borohydride

: 950578-98-0
((2,6-iPr2-C6H3)NC(tBu)CHC(tBu)N(2,6-iPr2-C6H3))Sc((μ-H)2B(C6F5)2)2

Guidance literature:: In toluene; byproducts: CH3B(C6F5)2; (inert conditions); addn. of toluene to mixt. of scandium compd. and 4 equiv. of boron compd., stirring for 30 min; filtration, evapn., addn. of hexane, sonication for 15 min, concg., cooling o -78°C for 30 min, filtration, evapn., elem. anal.;
DOI:10.1021/om700435v