165612-94-2

Basic information

• Product Name: BIS(PENTAFLUOROPHENYL)BORANE
• Synonyms: BIS(PENTAFLUOROPHENYL)BORANE
• CAS NO: 165612-94-2
• Molecular Formula: C₁₂HBF₁₀
• Molecular Weight: 345.931372
• Mol File: 165612-94-2.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 247.3±50.0 °C(Predicted)
• Appearance: /
• CAS DataBase Reference: BIS(PENTAFLUOROPHENYL)BORANE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(PENTAFLUOROPHENYL)BORANE(165612-94-2)
• EPA Substance Registry System: BIS(PENTAFLUOROPHENYL)BORANE(165612-94-2)

Safety Data

• Hazardous Substances Data: 165612-94-2(Hazardous Substances Data)

Usage

Chemical Description

Bis(pentafluorophenyl)borane is a boron compound with two pentafluorophenyl groups attached.

Upstream product

• 1109-15-5 tris(pentafluorophenyl)borate 
• 13292-87-0 dimethyl sulfide borane 
• 1066-35-9 dimethylmonochlorosilane 
• 2720-03-8 bis(pentafluorophenyl)boron chloride 
• 18164-03-9 phenylsilane-d3 
• 245043-30-5 bis(pentafluorophenyl)borylcyclohexane 
• 1333-74-0 hydrogen 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 148892-98-2 phenylbis(pentafluorophenyl)borane 
• 617-86-7 triethylsilane 
• 148892-97-1 tris(3,4,5-trifluorophenyl)borane 
• 344-04-7 bromopentafluorobenzene 

Downstream Products

• 80146-01-6 pentamethylcyclopentadienyliridium(III) PMe₃ dihydride 
• 245043-30-5 bis(pentafluorophenyl)borylcyclohexane 
• 211108-20-2 di(bis(pentafluorophenyl)boryl)C=CH(pentafluorophenyl) 
• 211108-19-9 di(bis(pentafluorophenyl)boryl)C=CHPh 
• 211108-17-7 di(bis(pentafluorophenyl)boryl)C=CH-t-Bu 
• 266311-34-6 [Mo(C₅H₅)2(H)(H₂B(C₆F₅)2)] 
• 266311-28-8 [W(C₅H₅)(C₅H₄B(C₆F₅)2H)H₃] 
• 273200-60-5 [(η5-C5H5)2Ti(μ-H)2B(C6F5)2] 
• 170151-48-1 methylbis(pentafluorophenyl)borane 
• 199607-95-9 (pentafluorophenyl)2B(benzyl) 
• 208184-25-2 Cp2ZrCl[(μ-H)2B(pentafluorophenyl)2] 
• 167896-11-9 Cp2Zr(μ-H)2[CH2(B(pentafluorophenyl)2)2] 
• 208184-27-4 [(pentafluorophenyl)2B]2CHPh 

Relevant articles and documents

Hydroboration of Phosphaalkynes by HB(C6F5)2

The hydroboration of phosphaalkynes with Piers’ borane (HB(C6F5)2) generated unusual phosphaalkenylboranes [RCH=PB(C6F5)2]2that persisted as dimers in both solution and the solid state. These P2B2heterocycles underwent ring opening when subjected to nucleophiles, such as pyridine and tert-butylisocyanide, to yield monomeric phosphaalkenylborane adducts RCH=PB(C6F5)2(L). DFT calculations were performed to probe the nature of the interaction of phosphaalkynes with boranes.

Facile activation of H-H and Si-H bonds by boranes

The borane B(C6F5)3 is a precatalyst for H/Dexchange between H2 and deuterium-labeled silanes (D 3SiPh, D2SiMePh, DSiMe2Ph, DSiEt3). Experimental and DFT studies revea

Silica Nanopowder Supported Frustrated Lewis Pairs for CO2Capture and Conversion to Formic Acid

Treatment of hydroxylated silica nanopowders S1 and allyl-functionalized silica nanopowders S2 with 3-(diphenylborano)- or 3-bis(pentafluorophenylborano)propyltrimethoxysilane or 2-(diphenylphosphino)- or 2-(dicyclohexylphosphino)ethyltriethoxysilane gene

Bis(pentafluorophenyl)phenothiazylborane-an intramolecular frustrated Lewis pair catalyst for stannane dehydrocoupling

We synthesized a novel Lewis acidic aminoborane containing a phenothiazyl substituent and demonstrated its potential to catalytically promote the dehydrocoupling of tin hydrides. The observed reactivity would imply a homolytic frustrated Lewis pair type mechanism, however computational analysis suggests a heterolytic mechanism for this reaction. This result represents one of the first frustrated Lewis pair systems to dehydrocouple stannanes in a heterolytic fashion.