methionine sulfone

Base Information

• Chemical Name: methionine sulfone
• CAS No.: 1118-85-0
• Molecular Formula: C₅H₁₁NO₄S
• Molecular Weight: 181.213
• Mol file: 1118-85-0.mol

Synonyms:

Chemical Property of methionine sulfone

Chemical Property:

• Vapor Pressure: 2.26E-09mmHg at 25°C
• Boiling Point: 450.5oC at 760 mmHg
• Flash Point: 226.3oC
• PSA: 105.84000
• Density: 1.385g/cm3
• LogP: 0.61410

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methionine sulfone

There total 34 articles about methionine sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

L-methionine (63-68-3,26062-47-5,58576-49-1) → L-methionine sulfone (7314-32-1,1118-85-0)

Guidance literature:

With urea hydrogen peroxide adduct; In ethanol; at 20 ℃; for 0.25h;

DOI:10.1016/j.catcom.2020.105931

Reference yield: 50.0%

L-methionine sulfoxide (3226-65-1,86631-49-4,779988-65-7) + trans-5-chloro-6-hydroperoxy-5,6-dihydrothymine (110815-41-3,112983-29-6,144208-80-0) → L-methionine sulfone (7314-32-1,1118-85-0) + trans-5-chloro-6-hydroxy-5,6-dihydrothymine (2075-32-3,7311-23-1)

Guidance literature:

In water-d2; for 72h;

DOI:10.1246/cl.1987.841

Reference yield: 35.0%

2-Acetylamino-4-methanesulfonyl-butyric acid → L-methionine sulfone (7314-32-1,1118-85-0)

Guidance literature:

With acylase from Aspergillus oryzae; water; at 20 - 37 ℃;

DOI:10.1016/S0957-4166(97)00400-X

upstream raw materials:

L-methionine

N-formyl-L-methionine S,S-dioxide

L-methionine sulfoxide

trans-5-chloro-6-hydroperoxy-5,6-dihydrothymine

Refernces

• 1、 Iselin,B.. "". . p. 61 - 78. Retrieved 1961.
• 2、 Kolb,Toennies. "-". . p. 723. Retrieved 1940.
• 3、 Lazar,Sheppard. "Fluorinated analogs of leucine, methionine, and valine.". . p. 138 - 140. Retrieved 1968.
• 4、 Carraro, Mauro,Nsouli, Nadeen,Oelrich, Holger,Sartorel, Andrea,Soraru, Antonio,Mal, Sib Sankar,Scorrano, Gianfranco,Walder, Lorenz,Kortz, Ulrich,Bonchio, Marcella. "Reactive ZrIV and HfIV butterfly peroxides on polyoxometalate surfaces: Bridging the gap between homogeneous and heterogeneous catalysis". . p. 8371 - 8378. Retrieved 2011.
• 5、 ?or?evi?, Luka,Cai, Kang,Chen, Hongliang,Chen, Xiao-Yang,Feng, Yuanning,Jaynes, Tyler,Jiao, Yang,Mao, Haochuan,Qiu, Yunyan,Stoddart, J. Fraser,Stupp, Samuel I.,Wasielewski, Michael R.,Young, Ryan M.,Zhang, Long. "A Donor-Acceptor [2]Catenane for Visible Light Photocatalysis". . p. 8000 - 8010. Retrieved 2021.