(+)-citronellol

Base Information

• Chemical Name: (+)-citronellol
• CAS No.: 5713-07-5
• Molecular Formula: C₁₀H₂₀O
• Molecular Weight: 156.268
• Mol file: 5713-07-5.mol

Synonyms:

Chemical Property of (+)-citronellol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (+)-citronellol

There total 10 articles about (+)-citronellol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3,7-dimethyl-7-octen-1-ol acetate (141-11-7) → 3,7-dimethyl-oct-7-en-1-ol (5713-07-5,6812-78-8,141-25-3)

Guidance literature:

With potassium hydroxide; In methanol; for 4h; Heating;

DOI:10.1023/A:1014439914429

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 2,6-dimethyl-6-heptenyl chloride → 3,7-dimethyl-oct-7-en-1-ol (5713-07-5,6812-78-8,141-25-3)

Guidance literature:

2,6-dimethyl-6-heptenyl chloride; With magnesium; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

formaldehyd; In tetrahydrofuran; for 18.5h; Reagent/catalyst; Solvent; Temperature; Reflux; Inert atmosphere;

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 2,6-dimethyl-6-heptenyl chloride → 3,7-dimethyl-oct-7-en-1-ol (5713-07-5,6812-78-8,141-25-3) + 3,7-dimethyl-7-octenyl formate

Guidance literature:

2,6-dimethyl-6-heptenyl chloride; With magnesium; In tetrahydrofuran; Inert atmosphere;

formaldehyd; In tetrahydrofuran; at 20 ℃; for 63.25h; Reflux; Inert atmosphere;

upstream raw materials:

3,7-dimethyl-7-octen-1-ol acetate

8-acetoxy-6-methyloctan-2-one

1-acetoxy-5-bromo-3-methylpentane

ethyl 2-acetyl-7-acetoxy-5-methylheptanoate

Downstream raw materials:

3,7-dimethyl-1-octanal

Rhodinylacetat

6,7-epoxycitronellol

tetrahydrogeraniol

Refernces

• 1、 Ishmuratov,Yakovleva,Galyautdinova,Faifer,Kharisov,Zorin,Tolstikov. "Universal approach to the synthesis of juvenoid hydroprene and methoprene from 4-methyltetrahydropyran". . p. 486 - 489. Retrieved 2007/10/03.