Cyclohexane, (dichloromethylene)-

Base Information

• Chemical Name: Cyclohexane, (dichloromethylene)-
• CAS No.: 1122-55-0
• Molecular Formula: C7H10Cl2
• Molecular Weight: 165.062
• DSSTox Substance ID: DTXSID00467699
• Nikkaji Number: J2.275.251K
• Wikidata: Q82294750
• Mol file: 1122-55-0.mol

Synonyms:(dichloromethylene)cyclohexane;1122-55-0;Cyclohexane, (dichloromethylene)-;dichloromethylidenecyclo hexane;SCHEMBL10561925;DTXSID00467699

Chemical Property of Cyclohexane, (dichloromethylene)-

Chemical Property:

• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 164.0159557
• Heavy Atom Count: 9
• Complexity: 115

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(=C(Cl)Cl)CC1

Technology Process of Cyclohexane, (dichloromethylene)-

There total 14 articles about Cyclohexane, (dichloromethylene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

tetrachloromethane (56-23-5) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → (dichloromethylene)cyclohexane (1122-55-0)

Guidance literature:

With triphenylphosphine; In acetonitrile;

DOI:10.1016/0040-4039(88)85072-X

Reference yield: 90.0%

1-dichloromethyl-1-trimethylsilyloxy-cyclohexane (54034-84-3) → (dichloromethylene)cyclohexane (1122-55-0)

Guidance literature:

With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -60 ℃; for 4h;

Reference yield: 70.0%

Bromotrichloromethane (75-62-7) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → (dichloromethylene)cyclohexane (1122-55-0)

Guidance literature:

cyclohexanone; With hydrazine hydrate; In dimethyl sulfoxide;

Bromotrichloromethane; With ammonia; copper(l) chloride; In water; dimethyl sulfoxide; for 0.5h;

DOI:10.1007/s11172-005-0168-9

upstream raw materials:

Cyclohexyl-trichlormethyl-sulfon

1-dichloromethyl-1-trimethylsilyloxy-cyclohexane

diethyl (trichloromethyl)phosphonate

cyclohexanone

Downstream raw materials:

1-(chloromethylene)cyclohexane

methylenecyclohexane