[(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]

Base Information

• Chemical Name: [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]
• CAS No.: 252032-16-9
• Molecular Formula: C₄₂H₄₂Cl₂P₂Ru
• Molecular Weight: 780.719
• Mol file: 252032-16-9.mol

Synonyms:

Chemical Property of [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]

There total 1 articles about [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.1%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + α,α'-bis(diphenylphosphino)-p-xylene (71403-19-5) → [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] (252032-16-9)

Guidance literature:

In dichloromethane; N2-atmosphere; addn. of Ru-complex to ligand at -78°C, stirring for 30 min with warming to room temp.; vol. reduction, chromy. (SiO2, CH2Cl2, then MeCN), solvent removal; elem. anal.;

DOI:10.1021/ic990687s

Reference yield: 75.3%

borane-THF (14044-65-6) + [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] (252032-16-9) → [BH3*(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] (252032-17-0)

Guidance literature:

In dichloromethane; N2-atmosphere; addn. of borane to Ru-complex at -78°C, stirring (-78°C, 15 min), slow warming to room temp.; vol. reduction, chromy. (SiO2, CH2Cl2/MeCN), evapn.;

DOI:10.1021/ic990687s

Reference yield: 54.0%

[2,2,2-(PPh3)2(CO)-nido-2-OsB5H9] (87370-05-6) + [(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2] (252032-16-9) → [2,2,2-(Ph3P)2(CO)-nido-2-OsB4H7-3-(BH2*dppx*Ru(p-cym)Cl2)]

Guidance literature:

In dichloromethane; (dppx*Ru(p-cym)Cl2) and (Ph3P)2(CO)OsB5H9 in CH2Cl2 were refluxed for 17h; solvent was removed, chromy.;

DOI:10.1016/j.ica.2004.10.015

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

α,α'-bis(diphenylphosphino)-p-xylene

Downstream raw materials:

[BH3*(α,α'-bis(diphenylphosphino)-p-xylene)*Ru(p-cymene)Cl2]