(2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

Base Information

Chemical Name:(2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol
CAS No.:162020-05-5
Molecular Formula:C₁₄H₁₉NO₄
Molecular Weight:265.309
Hs Code.:

Synonyms:

Suppliers and Price of (2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

Chemical Property:

Purity/Quality:

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Technology Process of (2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

There total 7 articles about (2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 796850-28-7
(2R,4aR,6R,7S,8R,8aR)-6-Azido-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

: 162020-05-5
(2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

Guidance literature:: With hydrogen; Raney nickel T-4; In ethanol; for 5h; Yield given; Ambient temperature;

Reference yield:

: 142789-89-7
(1R,3R,6R,10S)-10-hydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

: 162020-05-5
(2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

Guidance literature:: Multi-step reaction with 7 steps

1: pyridine / 1 h / Ambient temperature

2: 0.05M osmium tetraoxide/tert-butanol, N-methylmorpholine N-oxide / acetone; H₂O / 2 h / Ambient temperature

3: pyridine / 1 h at -15 deg C, 2 h at room temp.

4: pyridine / 8 h / Ambient temperature

5: 84 percent / sodium azide / dimethylformamide; H₂O / 2 h / 120 °C

6: 1M sodium methoxide / methanol; CH₂Cl₂ / 2 h / Ambient temperature

7: hydrogen / Raney nickel T-4 / ethanol / 5 h / Ambient temperature

With pyridine; osmium(VIII) oxide; sodium azide; hydrogen; sodium methylate; 4-methylmorpholine N-oxide; tert-butyl alcohol; Raney nickel T-4; In methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; acetone;

Reference yield:

: 163218-37-9
Benzoic acid (2R,4aR,8R,8aR)-2-phenyl-4a,5,8,8a-tetrahydro-4H-benzo[1,3]dioxin-8-yl ester

: 162020-05-5
(2R,4aR,6R,7S,8R,8aR)-6-Amino-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

Guidance literature:: Multi-step reaction with 6 steps

1: 0.05M osmium tetraoxide/tert-butanol, N-methylmorpholine N-oxide / acetone; H₂O / 2 h / Ambient temperature

2: pyridine / 1 h at -15 deg C, 2 h at room temp.

3: pyridine / 8 h / Ambient temperature

4: 84 percent / sodium azide / dimethylformamide; H₂O / 2 h / 120 °C

5: 1M sodium methoxide / methanol; CH₂Cl₂ / 2 h / Ambient temperature

6: hydrogen / Raney nickel T-4 / ethanol / 5 h / Ambient temperature

With pyridine; osmium(VIII) oxide; sodium azide; hydrogen; sodium methylate; 4-methylmorpholine N-oxide; tert-butyl alcohol; Raney nickel T-4; In methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; acetone;