[Os(η2-1,3-di(p-tolyl)triazenido)(P(OEt)3)4]BPh4

Base Information

• Chemical Name: [Os(η2-1,3-di(p-tolyl)triazenido)(P(OEt)3)4]BPh4
• CAS No.: 888033-26-9
• Molecular Formula: C₂₄H₂₀B*C₃₈H₇₄N₃O₁₂OsP₄
• Molecular Weight: 1398.35
• Mol file: 888033-26-9.mol

Synonyms:

Chemical Property of [Os(η2-1,3-di(p-tolyl)triazenido)(P(OEt)3)4]BPh4

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Os(η2-1,3-di(p-tolyl)triazenido)(P(OEt)3)4]BPh4

There total 1 articles about [Os(η2-1,3-di(p-tolyl)triazenido)(P(OEt)3)4]BPh4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

OsH2(P(OEt)3)4 (123753-20-8) + trifluorormethanesulfonic acid (1493-13-6) + sodium tetraphenyl borate (143-66-8) + methyl trifluoromethanesulfonate (333-27-7) + 1,3-di(p-tolyl)triaz-1-ene (785-86-4,813445-46-4) → [Os(η2-1,3-di(p-tolyl)triazenido)(P(OEt)3)4]BPh4 (888033-26-9)

Guidance literature:

With (C₂H₅)3N; In dichloromethane; toluene; (N2 or Ar); CF3SO3CH3 added to Os complex/toluene at -196°C, brought to room temp., stirred for 1 h, CF3SO3H added at -196°C, stirred for 1 h at room temp., ligand/toluene and CH2Cl2 added, stirred for 4 h, (C2H5)3N added, stirred for 3 h; concd. (vac.), treated with EtOH contg. NaB(C6H5)4, filtered, crystd. from CH2Cl2 and EtOH; elem. anal.;

DOI:10.1021/ic052063u

upstream raw materials:

OsH₂(P(OEt)3)4

trifluorormethanesulfonic acid

sodium tetraphenyl borate

methyl trifluoromethanesulfonate