Technology Process of Benzene, [[(2,2-dimethyl-3-butenyl)oxy]methyl]-
There total 1 articles about Benzene, [[(2,2-dimethyl-3-butenyl)oxy]methyl]- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
3-(benzyloxy)-2,2-dimethylpropan-1-ol;
With
1,10-Phenanthroline; potassium tert-butylate; copper(l) chloride;
In
fluorobenzene;
at 20 ℃;
for 0.166667h;
Inert atmosphere;
With
1-methyl-1H-imidazole; di-tert-butyl-diazodicarboxylate; oxygen;
In
fluorobenzene;
Reflux;
diazomethyl-trimethyl-silane;
With
triphenylphosphine; isopropyl alcohol;
In
fluorobenzene; diethyl ether;
at 60 ℃;
Inert atmosphere;
DOI:10.1021/ol802299d
- Guidance literature:
-
1-((2,2-dimethylbut-3-enyloxy)methyl)benzene;
With
2,2'-bis(1,3,2-benzodioxaborole);
(bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)rhodium (I); (S)-1-(2-diphenylphosphino-1-naphthyl)isoquinoline;
In
tetrahydrofuran;
at 20 ℃;
for 6h;
With
sodium hydroxide; dihydrogen peroxide;
Product distribution / selectivity;
- Guidance literature:
-
1-((2,2-dimethylbut-3-enyloxy)methyl)benzene;
With
2,2'-bis(1,3,2-benzodioxaborole);
(bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)rhodium (I); (S)-1-(2-diphenylphosphino-1-naphthyl)isoquinoline;
In
tetrahydrofuran;
at 20 ℃;
for 6h;
3-Bromopyridine;
With
caesium carbonate;
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride;
In
tetrahydrofuran; water;
at 80 ℃;
for 15h;
With
sodium hydroxide; dihydrogen peroxide;
for 6h;
Product distribution / selectivity;
