[Mo2(μ-acetato)2(μ-N,N'-diisopropylbenzamidinato)2]

Base Information

Chemical Name:[Mo2(μ-acetato)2(μ-N,N'-diisopropylbenzamidinato)2]
CAS No.:851427-72-0
Molecular Formula:C₃₀H₄₄Mo₂N₄O₄
Molecular Weight:716.584
Hs Code.:

Synonyms:

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Chemical Property of [Mo2(μ-acetato)2(μ-N,N'-diisopropylbenzamidinato)2]

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Technology Process of [Mo2(μ-acetato)2(μ-N,N'-diisopropylbenzamidinato)2]

There total 4 articles about [Mo2(μ-acetato)2(μ-N,N'-diisopropylbenzamidinato)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 14221-06-8,744215-74-5
tetrakis(acetato)dimolybdenum(II)

: lithium N,N′-bis(iso-propyl)benzamidinate

: 851427-79-7,851427-72-0
[Mo2(μ-acetato)2(μ-N,N'-diisopropylbenzamidinato)2]

Guidance literature:: In tetrahydrofuran; using Schlenk techniques; THF added by trap-to-trap transfer technique at -78°C to mixt. of Mo complex and Li compd. (molar ratio 1:2.1);warmed to room temp.; refluxed overnight; volatiles removed under reduced pressure; extd. with pentane; solvent evapd. under high vac.; elem. anal.;
DOI:10.1016/j.ica.2005.01.002

Reference yield: 33.0%

: 14221-06-8,744215-74-5
tetrakis(acetato)dimolybdenum(II)

: lithium N,N′-bis(iso-propyl)benzamidinate

: 80937-33-3
oxygen

: 851427-79-7,851427-72-0
[Mo2(μ-acetato)2(μ-N,N'-diisopropylbenzamidinato)2]

: [(Mo(η-N,N'-diisopropylbenzamidinato)oxo)2(μ-acetato)2(μ-oxo)]]

Guidance literature:: In tetrahydrofuran; using Schlenk techniques; THF added by trap-to-trap transfer technique at -78°C to mixt. of Mo complex and Li compd. (molar ratio 1:2.5);warmed to -30°C; cooled to -78°C; O2 (1 atm) introduced; warmed to room temp.; volatiles removed under reduced pressure; extd. with hexane; isolated byfractional recrystn.; elem. anal.;
DOI:10.1016/j.ica.2005.01.002

Reference yield:

: 14221-06-8,744215-74-5
tetrakis(acetato)dimolybdenum(II)

: lithium N,N′-bis(iso-propyl)benzamidinate

: 851427-79-7,851427-72-0
[Mo2(μ-acetato)2(μ-N,N'-diisopropylbenzamidinato)2]

: 851427-72-0
[Mo2(μ-acetato)2(η-N,N'-diisopropylbenzamidinato)2]

Guidance literature:: In tetrahydrofuran; using Schlenk techniques; THF added by trap-to-trap transfer technique at -78°C to mixt. of Mo complex and Li compd. (molar ratio 1:2.0);warmed to room temp.; reacted for several h; volatiles removed under reduced pressure; mixt. of two stereoisomeric Mocomplexes obtained; detd. by (1)H NMR spectra;
DOI:10.1016/j.ica.2005.01.002