hexacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe)

Base Information

• Chemical Name: hexacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe)
• CAS No.: 128178-28-9
• Molecular Formula: C₄₃H₄₂AsFe₂O₆PS
• Molecular Weight: 904.458
• Mol file: 128178-28-9.mol

Synonyms:

Chemical Property of hexacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hexacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe)

There total 1 articles about hexacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

hexacarbonyl(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron (84433-24-9,61793-17-7) + 1-diphenylarsino-2-diphenylphosphinoethane (23582-06-1) → hexacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe) (128178-28-9) + pentacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe) (128178-29-0)

Guidance literature:

In hexane; toluene; dropwise addn. of ligand in toluene to the Fe compd. in hexane under N2 and stirring at 20°C for 18 h; concn. (vac.), chromy. on silica gel, eluating with toluene-hexane, evapn. (vac.) and recrystn. from hexane; elem. anal.;

DOI:10.1016/0022-328X(90)87052-F

Reference yield: 74.0%

hexacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe) (128178-28-9) → tetracarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)2diiron (128178-31-4)

Guidance literature:

In hexane; Irradiation (UV/VIS); irradn. of the educt in hexane with a 125 W high pressure Hg-lamp for 2 h under N2; concn., chromy. on silica gel, elution with toluene-hexane and recrystn. from hexane-toluene; elem. anal.;

DOI:10.1016/0022-328X(90)87052-F

upstream raw materials:

hexacarbonyl(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron

1-diphenylarsino-2-diphenylphosphinoethane

Downstream raw materials:

tetracarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)2diiron