128178-29-0

Basic information

• Product Name: pentacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe)
• CAS NO: 128178-29-0
• Molecular Weight: 876.448
• Mol File: 128178-29-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pentacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe)(CAS DataBase Reference)
• NIST Chemistry Reference: pentacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe)(128178-29-0)
• EPA Substance Registry System: pentacarbonyl(1-diphenylphosphino-2-diphenylarsinoethane)(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron(Fe-Fe)(128178-29-0)

Safety Data

• Hazardous Substances Data: 128178-29-0(Hazardous Substances Data)

Upstream product

• 84433-24-9 hexacarbonyl(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron 
• 23582-06-1 1-diphenylarsino-2-diphenylphosphinoethane 

Relevant articles and documents

Uebergangsmetall-Heteroallen-Komplexe XXIII. Reaktionen des Cluster-Komplexes (Thioketen)Fe2(CO)6 mit Arsa-Chelat-Liganden

The cluster complex (thioketene)Fe2(CO)6 (2) reacts with ARPHOS (5) to give the adduct (thioketene)Fe2(CO)6(arphos) (7).In solution complex 7 very slowly cleaves CO to form the compound (thioketene)Fe2(CO)5 (arphos) (8).Heating or irradiation of 8 yields a dinuclear complex (thioketene)2Fe2(CO)4(arphos) (9) having two thioketene ligands in the molecule.Reaction of the cluster 2 with DIARS (6) gives the complex (thioketene)Fe2(CO)5 (diars) (13).The crystal structures of 7 and 13 have been determined by X-ray diffraction.