C₆₈H₁₂₄O₉S₂Si₃

Base Information

• Chemical Name: C₆₈H₁₂₄O₉S₂Si₃
• CAS No.: 127492-56-2
• Molecular Formula: C₆₈H₁₂₄O₉S₂Si₃
• Molecular Weight: 1234.12
• Mol file: 127492-56-2.mol

Synonyms:

Chemical Property of C₆₈H₁₂₄O₉S₂Si₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₈H₁₂₄O₉S₂Si₃

There total 1 articles about C₆₈H₁₂₄O₉S₂Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C76H129F3O13S3Si3 (127492-55-1) → C68H124O9S2Si3 (127492-56-2,127593-03-7)

Guidance literature:

With Li naphthalenide; In tetrahydrofuran; at -20 ℃; for 10h; Yield given;

DOI:10.1021/jo00296a042

Reference yield: 33.0%

C68H124O9S2Si3 (127492-56-2,127593-03-7) → (1E,9Z)-(3S,4R,5S,7R,8R,12S,14S,15R,16S,18R)-8-Allyl-7,15-bis-(tert-butyl-dimethyl-silanyloxy)-18-[1,3]dithian-2-yl-14,16-dimethoxy-1-((1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexyl)-2,4,10,12-tetramethyl-nonadeca-1,9-diene-3,5-diol (127492-57-3,127592-41-0) + (1E,9E)-(3S,4R,5S,7R,8R,12S,14S,15R,16S,18R)-8-Allyl-7,15-bis-(tert-butyl-dimethyl-silanyloxy)-18-[1,3]dithian-2-yl-14,16-dimethoxy-1-((1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexyl)-2,4,10,12-tetramethyl-nonadeca-1,9-diene-3,5-diol (127492-57-3,127592-41-0)

Guidance literature:

With pyridinium p-toluenesulfonate; In isopropyl alcohol; acetonitrile; at 70 ℃; for 46h;

DOI:10.1021/jo00296a042

Reference yield:

C68H124O9S2Si3 (127492-56-2,127593-03-7) → C81H149NO12SSi4

Guidance literature:

Multi-step reaction with 4 steps

1: 33 percent / pyridinium p-toluenesulfonate / propan-2-ol; acetonitrile / 46 h / 70 °C

2: 75 percent / 2,6-lutidine / CH₂Cl₂ / 0.33 h / Ambient temperature

3: N-chlorosuccinimide, AgNO₃, lutidine

With 2,6-dimethylpyridine; N-chloro-succinimide; lutidine; pyridinium p-toluenesulfonate; silver nitrate; In dichloromethane; isopropyl alcohol; acetonitrile;

DOI:10.1021/jo00296a042

upstream raw materials:

C₇₆H₁₂₉F₃O₁₃S₃Si₃

Downstream raw materials:

C₈₀H₁₄₁NO₁₃S₂Si₃

(1E,9Z)-(3S,4R,5S,7R,8R,12S,14S,15R,16S,18R)-8-Allyl-7,15-bis-(tert-butyl-dimethyl-silanyloxy)-18-[1,3]dithian-2-yl-14,16-dimethoxy-1-((1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexyl)-2,4,10,12-tetramethyl-nonadeca-1,9-diene-3,5-diol

(1E,9E)-(3S,4R,5S,7R,8R,12S,14S,15R,16S,18R)-8-Allyl-7,15-bis-(tert-butyl-dimethyl-silanyloxy)-18-[1,3]dithian-2-yl-14,16-dimethoxy-1-((1R,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexyl)-2,4,10,12-tetramethyl-nonadeca-1,9-diene-3,5-diol

C₆₆H₁₃₂O₉Si₄