{Ni(P(C₆H₅)2(SNCC₆H₅))2}

Base Information

Chemical Name:{Ni(P(C₆H₅)2(SNCC₆H₅))2}
CAS No.:134023-87-3
Molecular Formula:C₃₈H₃₀N₂NiP₂S₂
Molecular Weight:699.439
Hs Code.:

{Ni(P(C<sub>6</sub>H<sub>5</sub>)2(SNCC<sub>6</sub>H<sub>5</sub>))2}

Synonyms:

Suppliers and Price of {Ni(P(C₆H₅)2(SNCC₆H₅))2}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {Ni(P(C₆H₅)2(SNCC₆H₅))2}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {Ni(P(C₆H₅)2(SNCC₆H₅))2}

There total 4 articles about {Ni(P(C₆H₅)2(SNCC₆H₅))2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: nickel(II) nitrate hexahydrate

: 739-61-7
diphenyl(N-phenylthiocarbamoyl)phosphine

: 134023-87-3
{Ni(P(C₆H₅)2(SNCC₆H₅))2}

Guidance literature:: With NEt₃; In ethanol; addn. of the ligand to a stirred soln. of the Ni salt in EtOH, stirring (10 min), addn. of NEt3, stirring (30 min); vacuum filtration, washing (cold EtOH; Et2O), recrystn. (CHCl3), drying (vac., over P2O5); elem. anal.;
DOI:10.1039/dt9960002269

Reference yield: 73.0%

: 7440-02-0
nickel

: 103-72-0
phenyl isothiocyanate

: 829-85-6
diphenylphosphane

: 134023-87-3
{Ni(P(C₆H₅)2(SNCC₆H₅))2}

Guidance literature:: In acetonitrile; Electrolysis; electrolysis performed at 10 V and 20 mA for 2 h; electrolyte: tetraethylammonium perchlorate;; formed oil dissolved in dichloromethane and precipitated by addition of acetonitrile; product was washed with cold acetonitrile and dried in vacuo; elem. anal.;;
DOI:10.1039/DT9910000011

Reference yield: 67.0%

: 133952-91-7
Ni(P(C₆H₅)2)*(PH(C₆H₅)2)

: 103-72-0
phenyl isothiocyanate

: 134023-87-3
{Ni(P(C₆H₅)2(SNCC₆H₅))2}

Guidance literature:: In dichloromethane; Ni(PPh2)2PPh2H was added to the soln. of PhNCS at room temp.; the soln. was left for 24 h;; the volume was reduced to 5 ml; addn. of acetonitrile; the precipitated crystals were collected, washed with acetonitrile and dried; elem. anal.;
DOI:10.1039/DT9910000011