phenyltrioxo(tetrahydrofuran)rhenium(VII)

Base Information

• Chemical Name: phenyltrioxo(tetrahydrofuran)rhenium(VII)
• CAS No.: 138693-72-8
• Molecular Formula: C₁₀H₁₃O₄Re
• Molecular Weight: 383.418
• Mol file: 138693-72-8.mol

Synonyms:

Chemical Property of phenyltrioxo(tetrahydrofuran)rhenium(VII)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyltrioxo(tetrahydrofuran)rhenium(VII)

There total 1 articles about phenyltrioxo(tetrahydrofuran)rhenium(VII) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

diphenylzinc (1078-58-6) + rhenium(VII) oxide → Zn(2+)*2ReO4(1-)*2C4H8O=Zn(ReO4)2(C4H8O)2 (125934-15-8) + phenyltrioxo(tetrahydrofuran)rhenium(VII) (138693-72-8)

Guidance literature:

In tetrahydrofuran; under N2, Ph2Zn added dropwise to Re2O7 (-78°C), warmed (room temp., 2 h), yellow soln., white pptn., stirred (1 h); solvent removed in vac., extraction (pentane), filtered, concentration, cooled (2 h, -78°C), filtered, dried in vac.; elem. anal.;

Reference yield: 11.0%

Quinuclidine (100-76-5) + phenyltrioxo(tetrahydrofuran)rhenium(VII) (138693-72-8) → phenyltrioxo(quinuclidine)rhenium(VII) (138667-92-2)

Guidance literature:

In pentane; under N2, quinuclidine added dropwise, yellow pptn.; elem. anal.;

Reference yield:

phenyltrioxo(tetrahydrofuran)rhenium(VII) (138693-72-8) → (η(1)-phenyl)trioxorhenium (131457-04-0)

Guidance literature:

In neat (no solvent); under N2, removal of THF under vacuum (2 h); elem. anal.;

upstream raw materials:

diphenylzinc

Downstream raw materials:

(η(1)-phenyl)trioxorhenium

phenyltrioxo(quinuclidine)rhenium(VII)