fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine))

Base Information

Chemical Name:fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine))
CAS No.:81616-71-9
Molecular Formula:C₃₆H₃₇Cl₂P₃Ru
Molecular Weight:734.587
Hs Code.:

fac-(ruthenium(II)(Cl<sub>2</sub>)(bis(3-(diphenylphosphino)propyl)phenylphosphine))

Synonyms:

Suppliers and Price of fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine))

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine))

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine))

There total 1 articles about fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 194497-67-1,41290-68-0,482618-33-7,59091-96-2,61779-29-1,64376-67-6,72904-47-3,75766-08-4,89395-66-4,90698-13-8
cis-{RuCl₂(Me₂SO)4}

: 34989-06-5
Bis<3-(diphenylphosphino)propyl>phenylphosphin

: 81616-71-9
fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine))

Guidance literature:: In acetone; benzene; soln. of TTP in benzene is added at room temp. to suspension of cis-(RuCl2(DMSO)4) in acetone under nitrogen, soln. is refluxed for 20 min, refluxing is continued for 30 h; filtn., washing (acetone, ether), drying (80°C, overnight); elem. anal.;

Reference yield: 84.0%

: 81616-71-9
fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine))

: 2923-28-6
silver trifluoromethanesulfonate

: fac-(ruthenium(II)(MeCN)3(bis(3-(diphenylphosphino)propyl)phenylphosphine))(triflate)2

Guidance literature:: In acetonitrile; (RuCl2(TTP)) and AgCF3SO3 are suspended in MeCN and refluxed for 24 h under nitrogen; filtn., concd. to dryness under reduced pressure, residue is taken up in MeCN, filtn., ether is added, left overnight, filtn., washing (ether), drying (room temp. over P2O5 for 12 h); elem. anal.;

Reference yield: 76.0%

: 81616-71-9
fac-(ruthenium(II)(Cl₂)(bis(3-(diphenylphosphino)propyl)phenylphosphine))

: 16836-95-6
silver(I) 4-methylbenzenesulfonate

: (P,P',P''-bis(3-(diphenylphosphino)propyl)phenylphosphine)ruthenium(II) ditosylate dihydrate

Guidance literature:: In dichloromethane; AgOTs added to a soln. of Ru complex at a molar ratio of 1.5:0.67; stirred at -20° for 10 h; ppt. filtered off, filtrate concd., Et2O added, kept at 0°, crystalline yellow ppt. filtered off; purified by recrystallization from hotbenzene; identified by elem. anal.;
DOI:10.1007/BF02494906