[Pd(C₆H₄N=C=N(C₆H₄Me-4)-2)(4-tert-butylpyridine)(2,2'-bipyridine)]triflate

Base Information

• Chemical Name: [Pd(C₆H₄N=C=N(C₆H₄Me-4)-2)(4-tert-butylpyridine)(2,2'-bipyridine)]triflate
• CAS No.: 769968-30-1
• Molecular Formula: CF₃O₃S*C₃₃H₃₂N₅Pd
• Molecular Weight: 754.141
• Mol file: 769968-30-1.mol

Synonyms:

Chemical Property of [Pd(C₆H₄N=C=N(C₆H₄Me-4)-2)(4-tert-butylpyridine)(2,2'-bipyridine)]triflate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(C₆H₄N=C=N(C₆H₄Me-4)-2)(4-tert-butylpyridine)(2,2'-bipyridine)]triflate

There total 2 articles about [Pd(C₆H₄N=C=N(C₆H₄Me-4)-2)(4-tert-butylpyridine)(2,2'-bipyridine)]triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-tert-butylpyridine (3978-81-2) + [Pd(C6H4N=C=N(C6H4Me-4)-2)I(2,2'-bipyridine)] (769968-25-4) + thallium(I) triflate (73491-36-8) → [Pd(C6H4N=C=N(C6H4Me-4)-2)(4-tert-butylpyridine)(2,2'-bipyridine)]triflate (769968-30-1)

Guidance literature:

In acetone; byproducts: TlI; (N2); addn. of ligand and thallium salt to a suspn. of palladium complexin acetone, stirring for 10 min; filtration through Celite, evapn., trituration with Et2O, filtration, washing ppt. with Et2O, drying in vac. overnight; elem. anal.;

DOI:10.1021/om049580p

Reference yield:

[2,2]bipyridinyl (366-18-7) + N-((2-iodophenylimino)methylene)-4-methylbenzenamine (769968-23-2) → [Pd(C6H4N=C=N(C6H4Me-4)-2)(4-tert-butylpyridine)(2,2'-bipyridine)]triflate (769968-30-1)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: acetone

In acetone; toluene;

DOI:10.1021/om049580p

upstream raw materials:

4-tert-butylpyridine

[Pd(C₆H₄N=C=N(C₆H₄Me-4)-2)I(2,2'-bipyridine)]

thallium(I) triflate

[2,2]bipyridinyl