phenylene-1-bis[(triphenylphosphine)gold(I)]sulfonio-3-[(triphenylphosphine)gold(I)]thiolate tetrafluoroborate

Base Information

Chemical Name:phenylene-1-bis[(triphenylphosphine)gold(I)]sulfonio-3-[(triphenylphosphine)gold(I)]thiolate tetrafluoroborate
CAS No.:448280-28-2
Molecular Formula:BF₄*C₆₀H₄₉Au₃P₃S₂
Molecular Weight:1604.81
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenylene-1-bis[(triphenylphosphine)gold(I)]sulfonio-3-[(triphenylphosphine)gold(I)]thiolate tetrafluoroborate

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Technology Process of phenylene-1-bis[(triphenylphosphine)gold(I)]sulfonio-3-[(triphenylphosphine)gold(I)]thiolate tetrafluoroborate

There total 1 articles about phenylene-1-bis[(triphenylphosphine)gold(I)]sulfonio-3-[(triphenylphosphine)gold(I)]thiolate tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 13755-29-8
sodium tetrafluoroborate

: 626-04-0
3-mercaptothiophenol

: 53317-87-6
tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

: 448280-28-2
phenylene-1-bis[(triphenylphosphine)gold(I)]sulfonio-3-[(triphenylphosphine)gold(I)]thiolate tetrafluoroborate

Guidance literature:: In dichloromethane; byproducts: H2O; a soln. of complex in CH2Cl2 was treated with a soln. of dithiol in CH2Cl2 and a small quantity of NaBF4 at 20°C for 1 h (N2); ppt. was filtered off, crystd. upon addn. of pentane and cooling to -20°C, crystals were dried in vac.; elem. anal.;
DOI:10.1021/ic020107i