di[((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(tetrahydrofurane)yttrium(III)](μ-(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamido)-1,1'-binaphthyl) - toluene (1/1)

Base Information

Chemical Name:di[((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(tetrahydrofurane)yttrium(III)](μ-(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamido)-1,1'-binaphthyl) - toluene (1/1)
CAS No.:1235862-03-9
Molecular Formula:C₇H₈*C₉₈H₁₀₀N₁₂O₂Y₂
Molecular Weight:1747.9
Hs Code.:

di[((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(tetrahydrofurane)yttrium(III)](μ-(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamido)-1,1'-binaphthyl) - toluene (1/1)

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Chemical Property of di[((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(tetrahydrofurane)yttrium(III)](μ-(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamido)-1,1'-binaphthyl) - toluene (1/1)

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Technology Process of di[((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(tetrahydrofurane)yttrium(III)](μ-(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamido)-1,1'-binaphthyl) - toluene (1/1)

There total 2 articles about di[((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(tetrahydrofurane)yttrium(III)](μ-(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamido)-1,1'-binaphthyl) - toluene (1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: disodium (R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl

: chloro((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(dimethoxyethane)yttrium(III) - toluene - benzene (2/1/1)

: 1235862-03-9
di[((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(tetrahydrofurane)yttrium(III)](μ-(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamido)-1,1'-binaphthyl) - toluene (1/1)

Guidance literature:: In tetrahydrofuran; Y complex treated with 0.5 equiv. of ligand in THF; recrystd. from toluene;
DOI:10.1016/j.inoche.2010.01.008

Reference yield: 54.0%

: 1228437-50-0
(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamino)-1,1'-binaphthyl

: 10361-92-9,61894-01-7
yttrium(III) chloride

: 108-88-3,15644-74-3,16713-13-6
toluene

: 1235862-03-9
di[((R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrolid-2-ylmethyleneamide)-1,1'-binaphthyl)(tetrahydrofurane)yttrium(III)](μ-(R)-5,5',6,6',7,7',8,8'-octahydro-2,2'-bis(pyrrol-2-ylmethyleneamido)-1,1'-binaphthyl) - toluene (1/1)

Guidance literature:: With NaH; In 1,2-dimethoxyethane; 1.5 equiv. of binaphthyl deriv. treated with excess of NaH in DME, reaction with YCl3 in DME;
DOI:10.1016/j.inoche.2010.01.008