Yttrium(III) chloride

Base Information

• Chemical Name: Yttrium(III) chloride
• CAS No.: 10361-92-9
• Molecular Formula: Cl3Y
• Molecular Weight: 195.265
• Hs Code.: 28469026
• UNII: 11521XLD38
• DSSTox Substance ID: DTXSID2042515
• Nikkaji Number: J44.256I
• Wikipedia: Yttrium(III)_chloride
• Mol file: 10361-92-9.mol

Synonyms:YCl3;yttrium chloride;yttrium chloride hexahydrate;yttrium chloride, (88)Y-labeled;yttrium chloride, (90)Y-labeled;yttrium chloride, (91)Y-labeled

Chemical Property of Yttrium(III) chloride

Chemical Property:

• Appearance/Colour: powder
• Melting Point: 721 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 2.67 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Storage Temp.: 2-8°C
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water, ethanol and pyridine.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 193.812396
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99.99% ^*data from raw suppliers

Yttrium(III) chloride, anhydrous (99.9%-Y) (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Y+3]
• Description: Yttrium(III) chloride is an inorganic compound of yttrium and chloride. It exists in two forms, the hydrate (YCl3(H2O)6) and an anhydrous form (YCl3). Both are colourless solids that are highly soluble in water and deliquescent.Yttrium(III) chloride is used as a precursor for titanium-containing ceramics. It is used as an analytical reagent, as a catalyst and in superconductors. It is also used in the production of yttrium alkyl alkoxide complexes.
• Uses: Yttrium chloride (YCl3) decomposes at the relatively low temperature of 100°C. This makes it useful as a reagent in chemical laboratories. Yttrium(III) chloride is used as a precursor for titanium-containing ceramics. It is used as an analytical reagent, as a catalyst and in superconductors. It is also used in the production of yttrium alkyl alkoxide complexes.

Technology Process of Yttrium(III) chloride

There total 43 articles about Yttrium(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hexaaquadichloroyttrium(III) chloride → yttrium(III) chloride (10361-92-9,61894-01-7)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Y compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 31.74%

yttrium(III) oxide + erbium(III) oxide + potassium chloride + chlorine (7782-50-5) → erbium(III) chloride (10138-41-7) + yttrium(III) chloride (10361-92-9,61894-01-7)

Guidance literature:

With pyrographite; In gas; byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and Y2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor;

DOI:10.1016/j.jallcom.2005.02.104

Reference yield:

yttrium(III) oxide + chlorine (7782-50-5) + aluminium (7429-90-5) → aluminum oxide (1333-84-2,1344-28-1) + yttrium(III) chloride (10361-92-9,61894-01-7)

Guidance literature:

In neat (no solvent); heating (200°C, vac.; 300°C, 2 d); separated by chemical transport;

upstream raw materials:

hydrogenchloride

yttrium(III) chloride hexahydrate

chlorine

yttrium(III) chloride hydrate

Downstream raw materials:

aluminum isopropoxide

yttrium(III) fluoride

sodium chloride

hydrogenchloride

Refernces

Synthesis and characterization of yttrium complexes bearing a bulky arylamido ancillary ligand

10.1016/j.ica.2007.08.010

The research focuses on the synthesis and characterization of yttrium complexes with a bulky arylamido ancillary ligand. The main reactants used in the experiments include anhydrous YCl3, arylamido lithium 2,6-iPr2C6H3NSiiPr3Li, LiCH2SiMe3, and THF as a solvent. The synthesis involved the reaction of YCl3 with arylamido lithium to form an anionic mono-arylamido-ligated yttrium dichloride complex (1), which was then alkylated with LiCH2SiMe3 to produce an anionic arylamido-ligated yttrium tris(alkyl) complex (2). The complexes were characterized using NMR spectroscopy, elementary analysis, and X-ray structural determination, which confirmed their structures and provided insights into their steric and electronic properties. The study aimed to understand the reactivity of rare earth metal complexes and explore the potential of arylamido ligands in modifying these properties.

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