(4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate

Base Information

Chemical Name:(4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate
CAS No.:151694-52-9
Molecular Formula:C₃₃H₃₃NO₁₁
Molecular Weight:619.625
Hs Code.:

(4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate

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Chemical Property of (4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate

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Technology Process of (4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate

There total 3 articles about (4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 62209-66-9
1,4,9,10-tetrahydro-5,8-dihydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracene

: 151694-52-9
(4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate

Guidance literature:: Multi-step reaction with 2 steps

1: 50 percent / calcium hydride / tetrahydrofuran / 1) 0 deg C, 6 h, sonication, 2) room temperature, 24 h, sonication

2: 2) 1 N HCl / 1) THF, room temperature, 2 days, 2) 0 deg C, 15 min

With hydrogenchloride; calcium hydride; In tetrahydrofuran;
DOI:10.1016/S0040-4020(01)80160-5

Reference yield:

: 62209-65-8
1,4,4a,9a-Tetrahydro-5,8-dihydroxy-1-methoxy-1,4-ethano-9,10-anthrachinon

: 151694-52-9
(4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate

Guidance literature:: Multi-step reaction with 3 steps

1: aq. NaOH, air / 0.5 h

2: 50 percent / calcium hydride / tetrahydrofuran / 1) 0 deg C, 6 h, sonication, 2) room temperature, 24 h, sonication

3: 2) 1 N HCl / 1) THF, room temperature, 2 days, 2) 0 deg C, 15 min

With hydrogenchloride; sodium hydroxide; calcium hydride; air; In tetrahydrofuran;
DOI:10.1016/S0040-4020(01)80160-5

Reference yield:

: 88146-60-5
1-tert-Butoxy-3-<(trimethylsilyl)oxy>butadiene

: 74827-80-8
(4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate

: 151694-52-9
(4-nitrophenyl)methyl-1,4,6,6a,7,8,9,10,10a,11-decahydro-10-(1,1-dimethylethoxy)-12-hydroxy-1-methoxy-6,8,11(7H)-trioxo-1,4-ethanonaphthacen-5-yl-carbonate

Guidance literature:: With hydrogenchloride; Yield given. Multistep reaction; 1) THF, room temperature, 2 days, 2) 0 deg C, 15 min;
DOI:10.1016/S0040-4020(01)80160-5