(4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate

Base Information

Chemical Name:(4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate
CAS No.:74827-80-8
Molecular Formula:C₂₅H₁₉NO₉
Molecular Weight:477.427
Hs Code.:

Synonyms:(4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate

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Chemical Property of (4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate

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Technology Process of (4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate

There total 9 articles about (4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 62209-66-9
1,4,9,10-tetrahydro-5,8-dihydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracene

: 4457-32-3
4-nitrobenzyl chloroformate

: 74827-80-8
(4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate

Guidance literature:: With calcium hydride; In tetrahydrofuran; 1) 0 deg C, 6 h, sonication, 2) room temperature, 24 h, sonication;
DOI:10.1016/S0040-4020(01)80160-5

Reference yield:

: 74827-79-5
1,4,4a,9,9a,10-hexahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl(4-nitrophenyl)methyl carbonate

: 74827-80-8
(4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate

Guidance literature:: With diethyl ether; potassium hydride; lead dioxide; tartaric acid; In tetrahydrofuran; Yield given; 1) -78 deg C, 0 deg C, 0.5 h; 2) 4 deg C, overnight;
DOI:10.1016/S0040-4020(01)91516-9

Reference yield:

: 2161-90-2
1-methoxy-1,3-cyclohexadiene

: 74827-80-8
(4-nitrophenyl)methyl 1,4,9,10-tetrahydro-8-hydroxy-1-methoxy-9,10-dioxo-1,4-ethanoanthracen-5-yl carbonate

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 20 °C

2: KH, PbO₂ / tetrahydrofuran

With potassium hydride; lead dioxide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00538a081