N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline

Base Information

Chemical Name:N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline
CAS No.:1301629-54-8
Molecular Formula:C₃₈H₂₇N₃S
Molecular Weight:557.718
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline

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Technology Process of N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline

There total 2 articles about N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 267221-88-5
4-(diphenylamino)phenylboronic pinacol ester

: 1301629-53-7
4-(5-bromothiophen-2-yl)-6-phenyl-2,2'-bipyridine

: 1301629-54-8
N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; water; at 65 ℃; for 14h; Inert atmosphere;
DOI:10.1021/ic1025679

Reference yield:

: 1137-94-6
1-(2-phenyl-2-oxoethyl)pyridinium iodide

: 1301629-54-8
N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline

Guidance literature:: Multi-step reaction with 2 steps

1: ammonium acetate / N,N-dimethyl-formamide / 14 h / 120 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran; water / 14 h / 65 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; ammonium acetate; potassium carbonate; In tetrahydrofuran; water; N,N-dimethyl-formamide; 1: Kr?hnke condensation / 2: Suzuki reaction;
DOI:10.1021/ic1025679

Reference yield: 71.1%

: 330680-47-2
trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

: 1301629-54-8
N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline

: 7732-18-5
water

: silver nitrate

: [Ru(N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline(-1H))(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)]nitrate dihydrate

Guidance literature:: With N-ethylmorpholine; In tetrahydrofuran; methanol; water; (N2); suspending of N,N-diphenyl-4-(5-(6-phenyl-2,2'-bipyridin-4-yl)thiophen-2-yl)aniline in MeOH:H2O:THF (5:1:1), addn. of Ru(CH3OOCC5H2N(C5H3NCOOCH3)2)Cl3 and N-ethylmorpholine, reflux for 16 h, addn. of AgNO3, stirring at reflux for 1.5 h; cooling, preabsorbing on silica, removal of solvent in vac., chromy. (SiO2; CH2Cl2/MeOH, 9:1); elem. anal.;
DOI:10.1021/ic200011m