tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Base Information

Chemical Name:tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside
CAS No.:121845-12-3
Molecular Formula:C₄₅H₆₁N₃O₁₀Si
Molecular Weight:832.079
Hs Code.:

tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Synonyms:

Suppliers and Price of tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

There total 4 articles about tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 100-39-0
benzyl bromide

: 121845-11-2
tert-butyldimethylsilyl 4-O-(3-O-allyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-2-deoxy-β-D-glucopyranoside

: 121845-12-3
tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; 1.) -15 deg C, 0.5 h; 2.) 0 deg C, 1 h;

Reference yield:

: 121865-28-9
tert-butyldimethylsilyl 2-azido-2-deoxy-4-O-(β-D-galactopyranosyl)-β-D-glucopyranoside

: 121845-12-3
tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) dibutyltin oxide, 2.) tetrabutylammonium iodide / 1.) MeOH, reflux, 15 h, 2.) toluene, 60 degC, 24 h

2: 24 percent / bis(4-nitrophenyl)phosphate hydrate / acetone / 18 h / Ambient temperature

3: 51 percent / NaH / dimethylformamide / 1.) -15 deg C, 0.5 h; 2.) 0 deg C, 1 h

With bis(p-nitrophenyl) phosphoric acid hydrate; tetra-(n-butyl)ammonium iodide; sodium hydride; di(n-butyl)tin oxide; In N,N-dimethyl-formamide; acetone;

Reference yield:

: 121845-06-5
tert-butyldimethylsilyl 4-O-(3-O-allyl-β-D-galactopyranosyl)-2-azido-2-deoxy-β-D-glucopyranoside

: 121845-12-3
tert-butyldimethylsilyl 4-O-(3-O-allyl-2-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-2-azido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 24 percent / bis(4-nitrophenyl)phosphate hydrate / acetone / 18 h / Ambient temperature

2: 51 percent / NaH / dimethylformamide / 1.) -15 deg C, 0.5 h; 2.) 0 deg C, 1 h

With bis(p-nitrophenyl) phosphoric acid hydrate; sodium hydride; In N,N-dimethyl-formamide; acetone;