4-(3-BROMOPHENYL)-1-BUTEN-4-OL

Base Information

• Chemical Name: 4-(3-BROMOPHENYL)-1-BUTEN-4-OL
• CAS No.: 114095-73-7
• Molecular Formula: C10H11BrO
• Molecular Weight: 227.101
• Mol file: 114095-73-7.mol

Synonyms:1-(3-bromophenyl)but-3-en-1-ol;1-(3'-bromophenyl)-3-buten-1-ol;1-(m-bromophenyl)-3-buten-1-ol;4-(3-Bromophenyl)-1-buten-4-ol;1-(3-Bromo-phenyl)-but-3-en-1-ol;1-(3-bromo-phenyl)but-3-en-1-ol;

Chemical Property of 4-(3-BROMOPHENYL)-1-BUTEN-4-OL

Chemical Property:

• Boiling Point: 93°C 0,1mm
• PSA: 20.23000
• LogP: 3.05860

Purity/Quality:

4-(3-BROMOPHENYL)-1-BUTEN-4-OL ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-(3-BROMOPHENYL)-1-BUTEN-4-OL

There total 9 articles about 4-(3-BROMOPHENYL)-1-BUTEN-4-OL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

m-bromobenzoic aldehyde (3132-99-8) + allyl bromide (106-95-6) → 1-(3-bromophenyl)-3-buten-1-ol (114095-73-7)

Guidance literature:

With magnesium; 1.) ether, 2.) ether, reflux, 20 min;

DOI:10.1021/ja00219a040

Reference yield: 88.0%

m-bromobenzoic aldehyde (3132-99-8) + allylmagnesium bromide (1730-25-2) → 1-(3-bromophenyl)-3-buten-1-ol (114095-73-7)

Guidance literature:

m-bromobenzoic aldehyde; allylmagnesium bromide; In diethyl ether; at 0 - 20 ℃; Inert atmosphere;

With hydrogenchloride; In diethyl ether; water;

Reference yield: 83.0%

m-bromobenzoic aldehyde (3132-99-8) + allyltributylstanane (24850-33-7) → 1-(3-bromophenyl)-3-buten-1-ol (114095-73-7)

Guidance literature:

With copper(II)/magnesium-lanthanum mixedoxide; In acetonitrile; at 65 ℃; for 5h;

DOI:10.1002/adsc.201901133

upstream raw materials:

m-bromobenzoic aldehyde

allyl bromide

1,3-dibromopropene

3-chloroprop-1-ene

Downstream raw materials:

3-(1-hydroxybut-3-en-1-yl)benzonitrile

1-(3-bromophenyl)-1-butanone

(1-(3-bromophenyl)but-3-enyloxy)(tert-butyl)dimethylsilane

C₁₀H₉BrO