(4-acetylphenyl(phenyl)methane)tricarbonylchromium

Base Information

Chemical Name:(4-acetylphenyl(phenyl)methane)tricarbonylchromium
CAS No.:113031-44-0
Molecular Formula:C₁₈H₁₄CrO₄
Molecular Weight:346.303
Hs Code.:

Synonyms:

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Chemical Property of (4-acetylphenyl(phenyl)methane)tricarbonylchromium

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Technology Process of (4-acetylphenyl(phenyl)methane)tricarbonylchromium

There total 4 articles about (4-acetylphenyl(phenyl)methane)tricarbonylchromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 32825-32-4
diphenylmethane tricarbonylchromium

: 113031-44-0,113031-43-9
(4'-acetylphenyl(phenyl)methane)tricarbonylchromium

: 113031-43-9,113031-44-0
(4-acetylphenyl(phenyl)methane)tricarbonylchromium

: 113031-45-1
{((C₆H₄CH₃CO)2CH₂)Cr(CO)3}

: 790-82-9
bis(4-acetylphenyl)methane

: 782-92-3
1-(4-benzylphenyl)ethanone

Guidance literature:: With aluminium trichloride; acetyl chloride; In dichloromethane; Friedel-Crafts acetylation; anhydrous AlCl3-powder in CH2Cl2 is stirred at 0°C under N2, addn. of acetylchloride in CH2Cl2, stirring (30 min), Cr-compd. is added dropwise within 30 min (stirring, 0°C), further stirring (room temp., 5 h); mixt. is poured into ice-water, sepn. of the layers, aq. layer is extd. with CH2Cl2, combined org. layers are washed (with water, aq. NaHCO3), dried (Na2SO4), concd. (vac., 40-50°C), chromy., main fraction (mixt. of Cr-compds.) is not separable;
DOI:10.1039/P19870000747

Reference yield:

: 32825-32-4
diphenylmethane tricarbonylchromium

: 113031-44-0,113031-43-9
(4'-acetylphenyl(phenyl)methane)tricarbonylchromium

: 113031-43-9,113031-44-0
(4-acetylphenyl(phenyl)methane)tricarbonylchromium

: 113031-45-1
{((C₆H₄CH₃CO)2CH₂)Cr(CO)3}

: 790-82-9
bis(4-acetylphenyl)methane

: 782-92-3
1-(4-benzylphenyl)ethanone

Guidance literature:: With aluminium trichloride; acetyl chloride; In dichloromethane; Friedel-Crafts acetylation; anhydrous AlCl3-powder in CH2Cl2 is stirred at 0°C under N2, addn. of acetylchloride in CH2Cl2, stirring (30 min), Cr-compd. is added dropwise within 30 min (stirring, 0°C), further stirring (room temp., 5 h); mixt. is poured into ice-water, sepn. of the layers, aq. layer is extd. with CH2Cl2, combined org. layers are washed (with water, aq. NaHCO3), dried (Na2SO4), concd. (vac., 40-50°C), chromy., main fraction (mixt. of Cr-compds.) is not separable;
DOI:10.1039/P19870000747

Reference yield:

: 782-92-3
1-(4-benzylphenyl)ethanone

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 113031-44-0,113031-43-9
(4'-acetylphenyl(phenyl)methane)tricarbonylchromium

: 113031-43-9,113031-44-0
(4-acetylphenyl(phenyl)methane)tricarbonylchromium

Guidance literature:: With α-picoline; In diethylene glycol; under N2; the ketone, the Cr-compd., 2-methylpyridine and diglyme are refluxed for 6 h; chromy. on silica gel, elution with benzene, evapn., the syrup contains the two Cr-complexes in the ratio ca 1:1 (determined by t.l.c.);
DOI:10.1039/P19870000747