trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

Base Information

• Chemical Name: trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)
• CAS No.: 1312897-19-0
• Molecular Formula: C₉₁H₁₃₇ClN₄P₂PtSiZn
• Molecular Weight: 1673.07

Synonyms:

Chemical Property of trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

There total 1 articles about trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

trans-dichloro-bis(tri-n-butylphosphine)platinum(II) (15391-01-2,15076-72-9,15390-92-8) + Zn(C6H13)4(CH3)4C20H2N4(C6H4C2(Si(CH3)3))(C6H4C2H) (1312897-29-2) → trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II) (1312897-19-0)

Guidance literature:

With CuI; In dichloromethane; diethylamine; mixt. of platinum complex and CuI was dissolved in CH2Cl2/Et2NH (1:1, v/v), soln. of porphyrin in CH2Cl2 was added at room temp., stirred at room temp. for 30 min; evapd. in vac., fractionally crystd. from CH2Cl2-MeOH, evapd. in vac., purified using soln. of CH2Cl2-pentane (20:80-30:70, v/v) containing 0.5%of Et3N;

DOI:10.1039/c0nj00819b

Reference yield: 98.0%

trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II) (1312897-19-0) + trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II) (1312897-33-8) → 3Pt(2+)*4Zn(2+)*2(CH3)3SiCCC6H4(C6H13)4(CH3)4C20H2N4C6H4C2(3-)*2CCC6H4(C6H13)4(CH3)4C20H2N4C6H4C2(4-)*6P(C4H9)3

Guidance literature:

With CuCl; In dichloromethane; diethylamine; mixt. of porphyrins and CuCl was dissolved in CH2Cl2/Et2NH (1:1, v/v), stirred at room temp. for 30 min; evapd. in vac., crystd. from CH2Cl2-MeOH, washed with MeOH, collected with CH2Cl2, evapd. in vac., crystd. from CH2Cl2-MeOH;

DOI:10.1039/c0nj00819b

Reference yield: 20.0%

bis-1,15-(1,4-ethynylbenzene)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl) zinc(II) porphyrin (1228152-74-6) + trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II) (1312897-19-0) → 5,15-bis[trans-(4-ethynylphenyl)-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)-ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]-bis-(tri-n-butylphosphine)platinum(II)]-3,7,13,17-tetramethyl-2,8,12,18-tetrahexyl-zinc(II)

Guidance literature:

With CuI; In dichloromethane; diethylamine; mixt. of platinum porphyrin and CuI was dissolved in CH2Cl2/Et2NH (1:1, v/v), soln. of non-platinum porphyrin in CH2Cl2 was added, stirred at room temp. for 1 h; evapd. in vac., chromy. (silica, 20:60-30-60, CH2Cl2-pentane) with 0.5 %Et3N;

DOI:10.1039/c0nj00819b

upstream raw materials:

trans-dichloro-bis(tri-n-butylphosphine)platinum(II)

Zn(C₆H₁₃)4(CH₃)4C₂₀H₂N₄(C₆H₄C₂(Si(CH₃)3))(C₆H₄C₂H)

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