pentacarbonylmanganate

Base Information

• Chemical Name: pentacarbonylmanganate
• CAS No.: 35816-56-9
• Molecular Formula: C₅MnO₅
• Molecular Weight: 194.99
• Mol file: 35816-56-9.mol

Synonyms:

Chemical Property of pentacarbonylmanganate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of pentacarbonylmanganate

There total 48 articles about pentacarbonylmanganate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

hexamanganese(I) (21331-06-6) → pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + dimanganese decacarbonyl (10170-69-1)

Guidance literature:

In acetonitrile; byproducts: CO; Electrochem. Process; 0.2 M TBAP, potentiostatically at -1.20 V; not isolated, detected by IR spectroscopy;

Reference yield: 61.0%

hexacarbonylmanganese(I) tetrafluoroborate (15557-71-8) → pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + dimanganese decacarbonyl (10170-69-1)

Guidance literature:

In acetonitrile; byproducts: CO; Electrolysis; 0.2 M n-Bu4NClO4, constant current 3 mA; monitoring of catholyte by cyclic voltammetry;

Reference yield: 60.0%

pentacarbonyl(tri-o-anisylphosphine)manganese(I) cation (104350-77-8) → pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + dimanganese decacarbonyl (10170-69-1) + Mn2(CO)8(P(C6H4OCH3)3)2 (104350-78-9)

Guidance literature:

In tetrahydrofuran; Electrochem. Process; 0.3 M n-Bu4ClO4, potentiostatically at -1.20 V; not isolated, detected by IR spectroscopy;

upstream raw materials:

pentacarbonyl[dicarbonyl(N,N′-diisopropyl-1,4-diazabutadiene)methylruthenium]manganese

[(CO)5Mn-Ru(Me)(CO)2(pyridine-2-carbaldehyde-N-isopropylimine)]

dimanganese decacarbonyl

aniline

Downstream raw materials:

dimanganese decacarbonyl

Mn₂(CO)8(triethylphosphine)2

Mn₂(CO)9(triethylphosphine)

tetracarbonylhydrido(triethylphosphine)manganese