dimanganese octacarbonyl di-(triphenyl phosphine)

Base Information

• Chemical Name: dimanganese octacarbonyl di-(triphenyl phosphine)
• CAS No.: 15279-67-1
• Molecular Formula: C₄₄H₃₀Mn₂O₈P₂
• Molecular Weight: 858.541
• Mol file: 15279-67-1.mol

Synonyms:

Chemical Property of dimanganese octacarbonyl di-(triphenyl phosphine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimanganese octacarbonyl di-(triphenyl phosphine)

There total 49 articles about dimanganese octacarbonyl di-(triphenyl phosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + (acetonitrile)pentacarbonylmanganese(I) cation (27674-37-9) → dimanganese decacarbonyl (10170-69-1) + dimanganese octacarbonyl di-(triphenyl phosphine) (15279-67-1,10170-70-4) + tetracarbonylhydrido(triphenylphosphine)manganese (16925-29-4)

Guidance literature:

With tetrahydrofuran; triphenylphosphine; In tetrahydrofuran; in 10 mL of THF with 5E-3 M Mn(CO)5(1-) and 5E-3 M Mn(CO)5(NCMe)(1+) at 22°C under Ar, 0.1 mmol PPh3 added, react. complete within 5 min;

DOI:10.1021/om00152a010

Reference yield: 70.0%

(acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate (37504-44-2) + sodium pentacarbonyl manganate (13859-41-1) → dimanganese decacarbonyl (10170-69-1) + dimanganese octacarbonyl di-(triphenyl phosphine) (15279-67-1,10170-70-4) + tetracarbonylhydrido(triphenylphosphine)manganese (16925-29-4)

Guidance literature:

With tetrahydrofuran; triphenylphosphine; In tetrahydrofuran; in 10 mL of THF with 5E-3 M NaMn(CO)5 and 5E-3 M Mn(CO)5(NCMe)PF6 at 22°C under Ar, 0.1 mmol PPh3 added react. complete within 5 min;

DOI:10.1021/om00152a010

Reference yield: 66.0%

pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + pentacarbonyl(triphenylphosphine)manganese(I) cation (54039-45-1) → dimanganese decacarbonyl (10170-69-1) + dimanganese octacarbonyl di-(triphenyl phosphine) (15279-67-1,10170-70-4) + tetracarbonylhydrido(triphenylphosphine)manganese (16925-29-4)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5PPh3(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;

DOI:10.1021/om00152a010

upstream raw materials:

pentacarbonylmanganate

(acetonitrile)pentacarbonylmanganese(I) cation

pentacarbonyl(triphenylphosphine)manganese(I) cation

(acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate

Downstream raw materials:

IMn(CO)4(P(C₆H₅)3)

Mn(CO)4(P(C₆H₅)3)CH₂CCCH₃

ClMn(CO)4(P(C₆H₅)3)

ClMn(CO)3(P(C₆H₅)3)2