μ-dichlorobis[(carbonyl)(o-phenylene phenyl phosphite)rhodium(I)]

Base Information

• Chemical Name: μ-dichlorobis[(carbonyl)(o-phenylene phenyl phosphite)rhodium(I)]
• CAS No.: 157148-96-4
• Molecular Formula: C₂₆H₁₈Cl₂O₈P₂Rh₂
• Molecular Weight: 797.089
• Mol file: 157148-96-4.mol

Synonyms:

Chemical Property of μ-dichlorobis[(carbonyl)(o-phenylene phenyl phosphite)rhodium(I)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of μ-dichlorobis[(carbonyl)(o-phenylene phenyl phosphite)rhodium(I)]

There total 1 articles about μ-dichlorobis[(carbonyl)(o-phenylene phenyl phosphite)rhodium(I)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

tetracarbonyldi-μ-chlorodirhodium(I) + 2-phenoxy-1,3,2-benzodioxaphosphole (4591-40-6) → μ-dichlorobis[(carbonyl)(o-phenylene phenyl phosphite)rhodium(I)] (157148-96-4)

Guidance literature:

In dichloromethane; byproducts: CO; Ar, soln. of org. compound added dropwise to a soln. of Rh-compound at 20°C under stirring, stirred for 1 h; excess solvent removed in vacuo, precipitated with ether/pentane, centrifugated, washed (hexane), dried in air and vacuo; elem. anal.;

upstream raw materials:

2-phenoxy-1,3,2-benzodioxaphosphole