4591-40-6

Usage

InChI:InChI=1/C12H9O3P/c1-2-6-10(7-3-1)13-16-14-11-8-4-5-9-12(11)15-16/h1-9H

Upstream product

• 1641-40-3 pyrocatechol phosphorochloridite 
• 108-95-2 phenol 
• 3426-89-9 phenyl phosphorodichloridite 
• 120-80-9 benzene-1,2-diol 
• 5382-00-3 Diphenyl phosphorochloridite 
• 20621-24-3 N,N-diethyl-3-methyl-1,3,2-benzoaxaphosphol-2(3H)-amine 

Downstream Products

• 108668-92-4 Phenyl-o-phenylenthiophosphat 
• 54622-74-1 C₁₈H₂₁O₅P 
• 53799-42-1 2-Phenoxy-2,2-o-phenylendioxy-4,5-bis-(trifluormethyl)-2,2-dihydro-1,3,2-dioxaphospholen 
• 54622-75-2 C₁₈H₉F₁₂O₅P 
• 127522-22-9 (2-phenoxybenzo{1,3,2}dioxaphosphol)chromium(III)Cl₃(THF)2 
• 157148-96-4 μ-dichlorobis[(carbonyl)(o-phenylene phenyl phosphite)rhodium(I)] 
• 52961-95-2 2-phenoxy-2-oxo-4,5-benzo-1,3,2-dioxaphospholane 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 64672-14-6 Phosphoric acid 2-hydroxy-phenyl ester phenyl ester 
• 98-86-2 acetophenone 
• 60011-08-7 2,2-Dichloro-2-phenoxy-1,3-dioxa-2λ⁵-phospha-indan 
• 79519-95-2 o-Phenylendioxy-diphenoxy-chlorphosphoran 
• 41850-89-9 o-Phenylen-phenyl-phosphit-ozonid 
• 463-58-1 carbon oxide sulfide 

Relevant academic research and scientific papers

Reactions of N-aroxycarbonyltrichloroacetimidates with nucleophilic phosphorus derivatives

Aryl N-aroxycarbonyltrichloroacetimidates (Ar = Ph, 4-FC6H 4) react with diphenylphosphinite according to the scheme of the aza-Perkow reaction to give the corresponding aryl N-(1-aroxy-2,2-dichloro- vinyl)-N-diphenylphosphinoylcarba

Syntheses und NMR-Spektren phosphororganischer Antioxidantien und verwandter Verbindungen

The syntheses of various aliphatic, aromatic, sterically hindered, and cyclic organophosphorus compounds (phosphorous acid esters, esters chlorides and ester amides, hydrogen phosphites, phosphinates and phosphates) are reported, and general procedures for preparation are given.The compounds synthesized were investigated by means of 31P-, 1H- and 13C-n.m.r. spectroscopy, and the chemical shifts measured are listed.

Organophosphorus Antioxidants. X. The Hydroperoxide Decomposing Action of Phosphites, Phosphonites and Thiophosphites

The kinetics and mechanism of reactions of phosphites, phosphonites, thiophosphites and hydrogenphosphites with cumyl (CHP), t-butyl (TBHP) and α-tetralyl (THP) hydrogenperoxides has been studied by means of (31)P-n.m.r. spectroscopy, high performance liquid chromatography and iodometric titration.All three valent phosphorus compounds studied initially react with hydroperoxides stoichiometrically to give the corresponding P=O products and alcohol.Some species are able to decompose cumyl hydroperoxide catalytically to form phenol and aceton.Acyloin phosphites decompose CHP catalytically after a stoichiometric reaction as thiophosphites do.Tetramethylpiperidinyl phosphites ("HALS-phosphites") react with hydroperoxides only stoichiometrically but with high velocity.Phosphonites react with hydroperoxides in the same way as the corresponding phosphites.Their reactivity, however, is much higher.Hydrogenphosphites are less reactive than phosphites in the reaction with hydroperoxides.They are able to act catalytically.

OZONIDES DU PHOSPHORE STABILITE ET STEREOCHIMIE

A phosphorus ozonides series was obtained by reaction of ozone on various phosphites (1a-13a).The oxidative addition of ozone leads to trioxophosphetane ring formation branched on pentacoordinated (1b-9b) or hexacoordinated (10b-13b) phosphorus.The stability and stereochemistry of these compounds were studied.