Benzene, (1-methylenenonyl)-

Base Information

• Chemical Name: Benzene, (1-methylenenonyl)-
• CAS No.: 115045-59-5
• Molecular Formula: C16H24
• Molecular Weight: 216.367
• DSSTox Substance ID: DTXSID70457966
• Nikkaji Number: J2.284.481D
• Wikidata: Q82281068
• Mol file: 115045-59-5.mol

Synonyms:Benzene, (1-methylenenonyl)-;115045-59-5;2-Phenyl-1-decene;DTXSID70457966

Chemical Property of Benzene, (1-methylenenonyl)-

Chemical Property:

• XLogP3: 7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 216.187800766
• Heavy Atom Count: 16
• Complexity: 175

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCC(=C)C1=CC=CC=C1

Technology Process of Benzene, (1-methylenenonyl)-

There total 22 articles about Benzene, (1-methylenenonyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

1-bromo-octane (111-83-1) + 1-acetoxy-1-phenylethene (2206-94-2) → 2-phenyl-dec-1-ene (115045-59-5)

Guidance literature:

With 5,5'-dimethyl-2,2'-bipyridine; nickel(II) bromide diethylene glycol dimethyl ether; zinc; In N,N-dimethyl acetamide; at 40 ℃; for 24h; Sealed tube;

DOI:10.1002/anie.202114556

Reference yield: 81.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-octyl p-toluenesulfonate (3386-35-4) → 2-phenyldecan-1-ol (6583-61-5) + 2-phenyl-dec-1-ene (115045-59-5)

Guidance literature:

styrene; 1-octyl p-toluenesulfonate; With 2-cyclohexylethylmagnesium bromide; zirconocene dichloride; In tetrahydrofuran; at 55 ℃; for 4h;

With oxygen; In tetrahydrofuran; at 0 ℃;

DOI:10.1021/ol0160607

Reference yield: 76.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-octyl p-toluenesulfonate (3386-35-4) + benzaldehyde (100-52-7) → 2-phenyl-dec-1-ene (115045-59-5) + 1,3-diphenyl-1-undecanone

Guidance literature:

styrene; 1-octyl p-toluenesulfonate; With 2-cyclohexylethylmagnesium bromide; zirconocene dichloride; In tetrahydrofuran; at 55 ℃; for 4h;

benzaldehyde; In tetrahydrofuran; at 0 ℃;

DOI:10.1021/ol0160607

upstream raw materials:

1,1-dibromo-2-phenyldec-1-ene

2-bromodec-1-ene

phenylacetylene

styrene