η6-[(3,6-dimethylcyclohexen-4-yl)benzene]chromium tricarbonyl

Base Information

• Chemical Name: η6-[(3,6-dimethylcyclohexen-4-yl)benzene]chromium tricarbonyl
• CAS No.: 1384525-90-9
• Molecular Formula: C₁₇H₁₈CrO₃
• Molecular Weight: 322.324
• Mol file: 1384525-90-9.mol

Synonyms:

Chemical Property of η6-[(3,6-dimethylcyclohexen-4-yl)benzene]chromium tricarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of η6-[(3,6-dimethylcyclohexen-4-yl)benzene]chromium tricarbonyl

There total 2 articles about η6-[(3,6-dimethylcyclohexen-4-yl)benzene]chromium tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

3,6-dimethyl-4-phenylcyclohexene (1384840-63-4,19003-62-4,19003-63-5) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → η6-[(3,6-dimethylcyclohexen-4-yl)benzene]chromium tricarbonyl (1384525-90-9)

Guidance literature:

In octane; diethylene glycol dimethyl ether; ligand, Cr(CO)6 and diglyme-octane 1:1 refluxed at 160°C for 18 hunder Ar; filtered with Al2O3 layer, solvent evapd. in vacuo;

DOI:10.1007/s11172-011-0322-5

Reference yield: 40.0%

η6-(vinylbenzene)tricarbonylchromium(0) (1003605-44-4,31870-79-8) + hexa-2,4-diene (592-46-1) → η6-[(3,6-dimethylcyclohexen-4-yl)benzene]chromium tricarbonyl (1384525-90-9)

Guidance literature:

In octane; Cr-complex, ligand, octane heated at 150°C for 5 h, cooled; centrifuged, decanted, solvent evapd. in vacuo, extd. with hot hexane, placed in refrigerator;

DOI:10.1007/s11172-011-0322-5

upstream raw materials:

η6-(vinylbenzene)tricarbonylchromium(0)

hexa-2,4-diene

3,6-dimethyl-4-phenylcyclohexene

chromium⁽⁰⁾ hexacarbonyl