Digermirane, 1,1,2,2-tetrakis(2,6-diethylphenyl)-

Base Information

• Chemical Name: Digermirane, 1,1,2,2-tetrakis(2,6-diethylphenyl)-
• CAS No.: 115385-08-5
• Molecular Formula: C41H54Ge2
• Molecular Weight: 692.06
• DSSTox Substance ID: DTXSID40454109
• Nikkaji Number: J1.163.153C
• Mol file: 115385-08-5.mol

Synonyms:Digermirane, 1,1,2,2-tetrakis(2,6-diethylphenyl)-;115385-08-5;DTXSID40454109;1,1,2,2-Tetra(2,6-diethylphenyl)-1,2-digermacyclopropane

Chemical Property of Digermirane, 1,1,2,2-tetrakis(2,6-diethylphenyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 12
• Exact Mass: 692.2658053
• Heavy Atom Count: 43
• Complexity: 595

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC1=C(C(=CC=C1)CC)[Ge](C[Ge](C2=C(C=CC=C2CC)CC)C3=C(C=CC=C3CC)CC)C4=C(C=CC=C4CC)CC

Technology Process of Digermirane, 1,1,2,2-tetrakis(2,6-diethylphenyl)-

There total 1 articles about Digermirane, 1,1,2,2-tetrakis(2,6-diethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + hexakis(2,6-diethylphenyl)cyclotrigermane (94833-02-0) → 1,1,2,2-tetrakis(2,6-diethylphenyl)digermirane (115385-08-5)

Guidance literature:

In diethyl ether; cyclohexane; byproducts: N2; Irradiation (UV/VIS); Soln. of digermene, prepd. by irradiation of cyclotrigermane at room temp., is transferred to etheral soln. of CH2N2 under Ar at -78°C, mixt. is warmed to room temp.; crystn. (hexane), elem. anal.;

DOI:10.1021/om00098a036

Reference yield: 94.0%

selenium (7782-49-2) + 1,1,2,2-tetrakis(2,6-diethylphenyl)digermirane (115385-08-5) → tetrakis(2,6-diethylphenyl)-1,2,4-selenadigermetane (115406-97-8)

Guidance literature:

elem.anal.;

DOI:10.1021/om00098a036

Reference yield: 87.0%

sulfur (10544-50-0) + 1,1,2,2-tetrakis(2,6-diethylphenyl)digermirane (115385-08-5) → tetrakis(2,6-diethylphenyl)-1,2,4-thiadigermetane (115385-12-1)

Guidance literature:

elem.anal.;

DOI:10.1021/om00098a036

upstream raw materials:

diazomethane

hexakis(2,6-diethylphenyl)cyclotrigermane

Downstream raw materials:

bis(2,6-diethylphenyl)methoxymethylgermane

bis(2,6-diethylphenyl)methoxygermane

bis(2,6-diethylphenyl)(Me)2(1-germacyclopent-3-ene)

tetrakis(2,6-diethylphenyl)-1,2,4-thiadigermetane

Refernces

• 1、 Ando, Wataru,Tsumuraya, Takeshi. "Digermirane and azadigermiridine: Synthesis and reactions". . p. 1882 - 1883. Retrieved 2008/10/08.