Technology Process of Trigermirane, hexakis(2,6-diethylphenyl)-
There total 2 articles about Trigermirane, hexakis(2,6-diethylphenyl)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
magnesium; magnesium bromide;
In
tetrahydrofuran;
to mixt. of Mg, MgBr2 and THF was added a soln. of germane in THF, refluxed for 2 h, mixt. hydrolysed with HCl; mixt. extd. with ether, ext. evapd., hexane added;
DOI:10.1039/c39870001514
- Guidance literature:
-
With
magnesium; magnesium bromide;
In
tetrahydrofuran;
to mixt. of Mg, MgBr2 and THF was added a soln. of germane in THF and stirred for 2 h at room temp., mixt. hydrolysed with HCl; mixt. extd. with ether, ext. evapd., hexane added;
DOI:10.1039/c39870001514
- Guidance literature:
-
In
diethyl ether; cyclohexane;
byproducts: N2; Irradiation (UV/VIS); Soln. of digermene, prepd. by irradiation of cyclotrigermane at room temp., is transferred to etheral soln. of CH2N2 under Ar at -78°C, mixt. is warmed to room temp.; crystn. (hexane), elem. anal.;
DOI:10.1021/om00098a036
