2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester

Base Information

Chemical Name:2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester
CAS No.:287922-86-5
Molecular Formula:C₃₃H₃₄Cl₆N₂O₈
Molecular Weight:799.36
Hs Code.:

2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester

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Chemical Property of 2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester

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Technology Process of 2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester

There total 7 articles about 2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3587-60-8
Benzyloxymethyl chloride

: 287922-86-5
2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / i-Pr₂NEt

2: 96 percent / cationic iridium complex; I₂ / H₂O

3: Cs₂CO₃

With cationic iridium; iodine; caesium carbonate; N-ethyl-N,N-diisopropylamine; In water; 1: Etherification / 2: ether cleavage / 3: Addition;
DOI:10.1016/S0040-4039(00)01158-8

Reference yield:

: 100-39-0
benzyl bromide

: 287922-86-5
2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 89 percent / Ag₂O

2: 86 percent / BH₃*Me₂NH; BF₃*OEt₂ / CH₂Cl₂

3: 100 percent / i-Pr₂NEt

4: 96 percent / cationic iridium complex; I₂ / H₂O

5: Cs₂CO₃

With dimethylamine borane; cationic iridium; boron trifluoride diethyl etherate; iodine; caesium carbonate; N-ethyl-N,N-diisopropylamine; silver(l) oxide; In dichloromethane; water; 1: benzylation / 2: Reduction / 3: Etherification / 4: ether cleavage / 5: Addition;
DOI:10.1016/S0040-4039(00)01158-8

Reference yield:

: 183388-21-8
allyl 4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

: 287922-86-5
2,2,2-Trichloro-acetimidic acid (3R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethoxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 89 percent / Ag₂O

2: 86 percent / BH₃*Me₂NH; BF₃*OEt₂ / CH₂Cl₂

3: 100 percent / i-Pr₂NEt

4: 96 percent / cationic iridium complex; I₂ / H₂O

5: Cs₂CO₃

With dimethylamine borane; cationic iridium; boron trifluoride diethyl etherate; iodine; caesium carbonate; N-ethyl-N,N-diisopropylamine; silver(l) oxide; In dichloromethane; water; 1: benzylation / 2: Reduction / 3: Etherification / 4: ether cleavage / 5: Addition;
DOI:10.1016/S0040-4039(00)01158-8