Technology Process of C28H29BrO5
There total 7 articles about C28H29BrO5 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: diisobutylaluminium hydride / dichloromethane; toluene / 0.5 h / -78 °C / Inert atmosphere
2.1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 °C / Inert atmosphere
2.2: 3 h / -78 °C / Inert atmosphere
3.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / Inert atmosphere; Reflux
With
n-butyllithium; diisobutylaluminium hydride; diisopropylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; hexane; dichloromethane; ethyl acetate; toluene;
DOI:10.1021/jo400157d
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 °C / Inert atmosphere
1.2: 3 h / -78 °C / Inert atmosphere
2.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / Inert atmosphere; Reflux
With
n-butyllithium; diisopropylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; hexane; ethyl acetate;
DOI:10.1021/jo400157d
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: aluminum (III) chloride / dichloromethane / 2 h / 0 °C / Inert atmosphere
2.1: toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 5 h / 0 - 20 °C / Inert atmosphere
3.1: potassium carbonate / ethanol / 2 h / 70 °C / Inert atmosphere
3.2: 2 h / 70 °C / Inert atmosphere
4.1: diisobutylaluminium hydride / dichloromethane; toluene / 0.5 h / -78 °C / Inert atmosphere
5.1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 °C / Inert atmosphere
5.2: 3 h / -78 °C / Inert atmosphere
6.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / Inert atmosphere; Reflux
With
aluminum (III) chloride; n-butyllithium; diisobutylaluminium hydride; potassium carbonate; toluene-4-sulfonic acid; diisopropylamine; 3-chloro-benzenecarboperoxoic acid; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; ethanol; hexane; dichloromethane; ethyl acetate; toluene;
DOI:10.1021/jo400157d
