trans-(ruthenium)Cl₂(mesityl isocyanide)4

Base Information

Chemical Name:trans-(ruthenium)Cl₂(mesityl isocyanide)4
CAS No.:128507-03-9
Molecular Formula:C₄₀H₄₄Cl₂N₄Ru
Molecular Weight:752.792
Hs Code.:

trans-(ruthenium)Cl<sub>2</sub>(mesityl isocyanide)4

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Chemical Property of trans-(ruthenium)Cl₂(mesityl isocyanide)4

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Technology Process of trans-(ruthenium)Cl₂(mesityl isocyanide)4

There total 2 articles about trans-(ruthenium)Cl₂(mesityl isocyanide)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 20759-14-2,14898-67-0
ruthenium(III) chloride hydrate

: 57116-96-8
2-mesityl isocyanide

: 128507-03-9,155898-54-7
trans-(ruthenium)Cl₂(mesityl isocyanide)4

Guidance literature:: With zinc amalgam; In ethanol; stirring a mixt. of RuCl3*H2O and mesityl isocyanide in EtOH in the presence of an excess of zinc amalgam at room temp. for 2.5 h; decantn., removal of solvent in vacuo, chromy. on Al2O3 (CH2Cl2 as eluent), removal of solvent crystn. from CH2Cl2 and ether, elem. anal.;
DOI:10.1016/0022-328X(90)80008-N

Reference yield:

: 128507-03-9,155898-54-7
trans-(ruthenium)Cl₂(mesityl isocyanide)4

: 128507-03-9,155898-54-7
RuCl₂(CNC₆H₂(CH₃)3)4

Guidance literature:: In neat (no solvent, solid phase); solid-state isomerization on heating at 221-225°C;;
DOI:10.1016/0020-1693(93)03773-4

Reference yield: 12.4%

: ammonium hexafluorophosphate

: 128507-03-9,155898-54-7
trans-(ruthenium)Cl₂(mesityl isocyanide)4

: trans-((ruthenium)Cl₂(mesityl isocyanide)4)(PF₆)*0.5CH₂Cl₂

Guidance literature:: With Ce(SO₄)2; In dichloromethane; stirring of Ru-complex, Ce(SO4)2 and (NH4)(PF6) in CH2Cl2 for 2 h at room temp.; filtn., crystn. from CH2Cl2-ether;
DOI:10.1016/0022-328X(90)80008-N